Reaction of tris(1,10-phenanthroline) cobalt(III) perchlorate, nitromethane and an excess of base-I reaction with pyridine

dc.creatorBaraona, Ruth
dc.creatorRozenblum, Sylvia
dc.creatorZamudio, Walter
dc.date.accessioned2018-12-20T15:10:03Z
dc.date.available2018-12-20T15:10:03Z
dc.date.created2018-12-20T15:10:03Z
dc.date.issued1978
dc.identifierJournal of Inorganic and Nuclear Chemistry, Volumen 40, Issue 12, 2018, Pages 2043-2047
dc.identifier00221902
dc.identifier10.1016/0022-1902(78)80200-0
dc.identifierhttp://repositorio.uchile.cl/handle/2250/158120
dc.description.abstractKinetic studies of the [Co(phen)3] (ClO4)3 2H2O nitromethane pyridine reaction were made spectrophotometrically, by recording the appearance of a new absorption band at 474 nm. The reaction is first order with respect to all three reactants. Reaction products were isolated and attempts were made to purify them. A mechanism is proposed for the reaction involving the formation of Co(phen)33+CH2NO2- (ClO4)2. The rate determining step would be the rupture of a CH bond in the solvated nitromethane molecule. © 1978.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceJournal of Inorganic and Nuclear Chemistry
dc.titleReaction of tris(1,10-phenanthroline) cobalt(III) perchlorate, nitromethane and an excess of base-I reaction with pyridine
dc.typeArtículos de revistas


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