Artículos de revistas
Band shift in chromium (III) complexes with mixed ligands. A molecular orbital approach
Fecha
1969Registro en:
Journal of Inorganic and Nuclear Chemistry, Volumen 31, Issue 10, 2018, Pages 3203-3209
00221902
10.1016/0022-1902(69)80106-5
Autor
Bunel Torrealba, Sergio
Ibarra, C.
Adan, L.
Institución
Resumen
The shift of the first and second spin allowed bands due to the stepwise replacement of the nitrogen atoms in a complex of Cr(III) of the CrN6 type by oxygen atoms of water or of carboxylic groups is analyzed in terms of perturbational molecule orbital theory. The set of parameters necessary to account for this effect has been obtained. Results agree fairly well with experimental data. © 1969.