Artículo de revista
Solvent effect on the quenching of singlet oxygen by 3-methylindole
Fecha
2001Registro en:
Physical Chemistry Chemical Physics, Volumen 3, Issue 23, 2018, Pages 5222-5225
14639076
10.1039/b104673j
Autor
Lemp Miranda, Else
Pizarro, Nancy
Encinas, María Victoria
Zanocco Loyola, Antonio
Institución
Resumen
Detection of O2(1Δg) emission, λmax = 1270 nm, following laser excitation and steady-state methods were employed to measure total, kT, and chemical, kR, reaction rate constants for the reaction between 3-methylindole and singlet oxygen in several solvents. Values of kT range from 0.12 ± 0.008 × 107 M-1s-1 in n-heptane to 32.0 ± 1.12 × 107 M-1s-1 in D2O at pD = 7.4. Analysis of the solvent effect on kT by using the semiempirical and theoretical linear solvent free-energy relationship (LSER and TLSER) solvatochromic equations indicates that singlet oxygen deactivation by 3-methylindole is accelerated by solvents with large π* values. This result supports the participation of an exciplex intermediate with partial charge transfer character, leading to either chemical reaction or physical quenching. The contribution of chemical reaction to total quenching depends significantly on the solvent. Chemical reaction can be neglected in non-polar solvents, whereas in hydrogen-bond donor solvents,