dc.creator | Muñoz, Marcelo A. | |
dc.creator | Areche Medina, Carlos | |
dc.creator | San Martín Barrientos, Aurelio | |
dc.creator | Rovirosa, Juana | |
dc.creator | Joseph-Nathan, Pedro | |
dc.date.accessioned | 2018-12-20T14:41:27Z | |
dc.date.available | 2018-12-20T14:41:27Z | |
dc.date.created | 2018-12-20T14:41:27Z | |
dc.date.issued | 2009 | |
dc.identifier | Natural Product Communications Vol. 4 (8) 2009 | |
dc.identifier | 1934578X | |
dc.identifier | 15559475 | |
dc.identifier | http://repositorio.uchile.cl/handle/2250/157097 | |
dc.description.abstract | The absolute configuration of the pentacyclic ichthyotoxin stypotriol, a constituent of Stypopodium zonale, was deduced to be 3S,5R,8R,9R,10S,13S,14S-(-) -1 by vibrational circular dichroism spectroscopy of the derived triacetate 2 in comparison to DFT B3LYP/DGDZVP calculations. Compound 2, C33H46O7 having 300 electrons, is the largest natural product successfully studied by VCD to date. | |
dc.language | en | |
dc.rights | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
dc.source | Natural Product Communications | |
dc.subject | Absolute configuration | |
dc.subject | Stypotriol | |
dc.subject | VCD | |
dc.title | VCD determination of the absolute configuration of stypotriol | |
dc.type | Artículos de revistas | |