VCD determination of the absolute configuration of stypotriol

dc.creatorMuñoz, Marcelo A.
dc.creatorAreche Medina, Carlos
dc.creatorSan Martín Barrientos, Aurelio
dc.creatorRovirosa, Juana
dc.creatorJoseph-Nathan, Pedro
dc.date.accessioned2018-12-20T14:41:27Z
dc.date.available2018-12-20T14:41:27Z
dc.date.created2018-12-20T14:41:27Z
dc.date.issued2009
dc.identifierNatural Product Communications Vol. 4 (8) 2009
dc.identifier1934578X
dc.identifier15559475
dc.identifierhttp://repositorio.uchile.cl/handle/2250/157097
dc.description.abstractThe absolute configuration of the pentacyclic ichthyotoxin stypotriol, a constituent of Stypopodium zonale, was deduced to be 3S,5R,8R,9R,10S,13S,14S-(-) -1 by vibrational circular dichroism spectroscopy of the derived triacetate 2 in comparison to DFT B3LYP/DGDZVP calculations. Compound 2, C33H46O7 having 300 electrons, is the largest natural product successfully studied by VCD to date.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceNatural Product Communications
dc.subjectAbsolute configuration
dc.subjectStypotriol
dc.subjectVCD
dc.titleVCD determination of the absolute configuration of stypotriol
dc.typeArtículos de revistas


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