The crystal structure of a novel sulfenamide: (N,N-dibenzyl)bencenesulfenamide

dc.creatorBrito, Ivan
dc.creatorDíaz, Carlos
dc.creatorGonzález Moraga, Guillermo
dc.creatorRodriguez, Matias Lopez
dc.creatorManriquez, V.
dc.date.accessioned2018-12-20T14:26:56Z
dc.date.available2018-12-20T14:26:56Z
dc.date.created2018-12-20T14:26:56Z
dc.date.issued1999
dc.identifierBoletin de la Sociedad Chilena de Quimica, Volumen 44, Issue 4, 2018, Pages 459-462
dc.identifier03661644
dc.identifier10.4067/S0366-16441999000400009
dc.identifierhttps://repositorio.uchile.cl/handle/2250/156056
dc.description.abstractThe crystal structure of (N,N-dibenzyl)bencenesulfenamide, (C6H5)SN(CH2C6H5) 2 is described and compared with other sulfenamides and with its chromium pentacarbonyl complex. This structure belongs to a type of divalent sulphur compound and crystallized in the triclinic system, space group P ⊥ with a = 5.552(3), b = 11.527(4), c = 13.670(8) Å, α = 79.30(4), β= 89.90(4), ρ = 89.70(3)° and Dx = 1.284 g cm-3 with Z=2. The N-S distance is 1.681 (10) Å, which is significantly shorter than the reported for its chromium pentacarbonyl complex and than a single S-N bond [1.74 Å].
dc.languageen
dc.publisherSociedad Chilena de Quimica
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceBoletin de la Sociedad Chilena de Quimica
dc.subjectDivalent sulfur compounds
dc.subjectSulfenamides
dc.subjectSulfenic acid derivatives
dc.titleThe crystal structure of a novel sulfenamide: (N,N-dibenzyl)bencenesulfenamide
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución