Sulphurating and coordinating properties of N,N′-thiobismorpholine towards iron carbonyls

dc.creator	Diaz, Carlos
dc.date.accessioned	2018-12-20T14:11:49Z
dc.date.available	2018-12-20T14:11:49Z
dc.date.created	2018-12-20T14:11:49Z
dc.date.issued	1990
dc.identifier	Polyhedron, Volumen 9, Issue 8, 2018, Pages 1045-1049
dc.identifier	02775387
dc.identifier	10.1016/S0277-5387(00)81292-9
dc.identifier	https://repositorio.uchile.cl/handle/2250/154664
dc.description.abstract	The reactions of N,N′-thiobismorpholine, {A figure is presented}, with Fe(CO)5, Fe2(CO)9, Fe3(CO)11 and [(η5-C5H5)Fe(CO)2THF]BF4 were examined. Thiobismorpholine undergoes desulphurization towards Fe(CO)5 with formation of Fe3(CO)9S2, while the novel complex Fe(CO)4{A figure is presented} was isolated and characterized from the reaction with Fe2(CO)9. On the other hand, thiobismorpholine is somewhat unreactive towards Fe3(CO)11 but it undergoes SN fission with [(η5-C5H5)Fe(CO)2THF]BF4. © 1990.
dc.language	en
dc.rights	http://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rights	Attribution-NonCommercial-NoDerivs 3.0 Chile
dc.source	Polyhedron
dc.subject	Physical and Theoretical Chemistry
dc.subject	Inorganic Chemistry
dc.subject	Materials Chemistry
dc.title	Sulphurating and coordinating properties of N,N′-thiobismorpholine towards iron carbonyls
dc.type	Artículo de revista