The structure of the first supramolecular α-cyclodextrin complex with an aliphatic monofunctional carboxylic acid

dc.creatorRodríguez Llamazares, Saddys María
dc.creatorYutronic Sáez, Nicolás
dc.creatorJara Vergara, Paul
dc.creatorEnglert, Ulli
dc.creatorNoyong, Michael
dc.creatorSimon, Ulrich
dc.date.accessioned2018-12-20T14:11:40Z
dc.date.available2018-12-20T14:11:40Z
dc.date.created2018-12-20T14:11:40Z
dc.date.issued2007
dc.identifierEur. J. Org. Chem.2007, 4298–4300
dc.identifier1434193X
dc.identifier10990690
dc.identifier10.1002/ejoc.200700454
dc.identifierhttp://repositorio.uchile.cl/handle/2250/154584
dc.description.abstractThe crystal structure of the supramolecular complex between α-cyclodextrin and decanoic acid was determined: The aliphatic chain of the carboxylic acid is threaded through a head-to-head dimer of two cyclodextrin residues, resulting in a 1:2 stoichiometry. Head-to-head orientation is also observed between neighboring complexes. The overall degree of hydration with 25 water molecules per supramolecular complex is remarkably high
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceEuropean Journal of Organic Chemistry
dc.subjectCyclodextrins
dc.subjectInclusion compounds
dc.subjectPseudochannel structure
dc.subjectX-ray diffraction
dc.titleThe structure of the first supramolecular α-cyclodextrin complex with an aliphatic monofunctional carboxylic acid
dc.typeArtículos de revistas


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