π-strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers

dc.creatorDomingo, Luis R.
dc.creatorPérez, Patricia
dc.creatorContreras Ramos, Renato
dc.date.accessioned2018-12-20T14:11:15Z
dc.date.available2018-12-20T14:11:15Z
dc.date.created2018-12-20T14:11:15Z
dc.date.issued2006
dc.identifier1434193X
dc.identifier10.1002/ejoc.200500466
dc.identifierhttps://repositorio.uchile.cl/handle/2250/154524
dc.description.abstractSmall cycloalkynes possess a π-strain-induced electrophilicity related to the bending of the Csp3-Csp-Csp bond angle. For cyclopentyne and benzyne, the electrophilicity index defined in the context of density functional theory gives a coherent rationale for the reactivity of these cycloalkynes, which may act as electrophiles in polar cycloaddition reactions toward enol ethers. © Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceEuropean Journal of Organic Chemistry
dc.subjectCycloadditions
dc.subjectCycloalkynes
dc.subjectDensity functional calculations
dc.subjectElectrophilicity
dc.subjectStrain
dc.titleπ-strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers
dc.typeArtículo de revista


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