Quantitative characterization of the global philicity patterns of common diene/dienophile pairs in cycloaddition reactions II: the interacting pair model

dc.creatorPérez Méndez, Claudio
dc.creatorContreras Ramos, Renato
dc.date.accessioned2015-07-30T14:36:47Z
dc.date.available2015-07-30T14:36:47Z
dc.date.created2015-07-30T14:36:47Z
dc.date.issued2015
dc.identifierTetrahedron Letters 56 (2015) 1767–1770
dc.identifierdoi: 10.1016/j.tetlet.2015.01.199
dc.identifierhttps://repositorio.uchile.cl/handle/2250/132240
dc.description.abstractWe present a unified model of electrophilicity and nucleophilicity that considers the electrophile/nucleophile pair in an interacting regime, thereby avoiding the arbitrariness of defining them as the opposite ends of a unique reactivity scale. The model is validated against rate coefficients for the cycloaddition of azomethine ylides towards substituted acetylenes and Michael addition of a series of 1-(X-substituted phenyl)-2-propyn-1-ones towards hydrazine.
dc.languageen
dc.publisherElsevier
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 Chile
dc.subjectNucleophilicity
dc.subjectElectrophilicity
dc.subjectCycloaddition
dc.subjectMichael addition
dc.titleQuantitative characterization of the global philicity patterns of common diene/dienophile pairs in cycloaddition reactions II: the interacting pair model
dc.typeArtículo de revista


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