Artículo de revista
Remote regio- and stereocontrol by the sulfinyl group: Diels–Alder reaction of sulfinyl dienols and 8,8-dimethylnaphthalene-1,4,5(8H)-trione
Fecha
2013Registro en:
Tetrahedron: Asymmetry 24 (2013) 56–61
doi10.1016/j.tetasy.2012.11.017
Autor
Almodovar, Iriux
Cardona, Wilson
Delgado Castro, Tomás
Zapata Torres, Gerald Amilcar
Caroli Rezende, Marcos
Araya Maturana, Ramiro
Maestro, M. Carmen
García Ruano, José L.
Institución
Resumen
Diels–Alder cycloaddition of 8,8-dimethylnaphthalene-1,4,5(8H)-trione with diastereomeric hydroxysulfinyldienes
proceeded with high yields and good p-facial and regioselectivities. The hydroxysulfoxide
moiety controls the regio- and stereoselectivities, through hydrogen bonds in the suggested transition
state.