Mixed complexes of cobalt(III) with D-glucosamine and phenanthroline

dc.creator	Blasko, Andrei
dc.creator	Bunton, Clifford A.
dc.creator	Bunel Torrealba, Sergio
dc.creator	Moraga, Exequiel
dc.creator	Ibarra, Carmen
dc.creator	Parada Aliste, José
dc.date.accessioned	2011-06-10T15:44:59Z
dc.date.available	2011-06-10T15:44:59Z
dc.date.created	2011-06-10T15:44:59Z
dc.date.issued	1995
dc.identifier	Boletín de la Sociedad Chilena de Química 40: 449-454
dc.identifier	0366-1644
dc.identifier	https://repositorio.uchile.cl/handle/2250/121265
dc.description.abstract	Examination of 1H chemical shifts of a complex of D-glucosamine with bis-phenanthroline cobalt(III)shows that the dominant ∆-complex is formed from α-D-glucosamine. A molecular mechanics simulation of the structure of this complex indicates that the sugar residue is not markedly perturbed by complexation of Co(III) at the 1-alkoxide and 2-amino groups. The circular dichroism spectrum of the complex formed in solution agrees with that of the isolated material.
dc.language	en
dc.publisher	Sociedad Chilena de Química
dc.subject	Cobalt(III)
dc.title	Mixed complexes of cobalt(III) with D-glucosamine and phenanthroline
dc.type	Artículo de revista