An Electron Spin Resonance (ESR) investigation of potential ligands of inorganic interest with nitro substituents

dc.creatorAtria Salas, Ana María
dc.creatorValenzuela Pedevila, Jorge
dc.creatorContreras, M.
dc.creatorZolezzi Carvallo, Santiago
dc.date.accessioned2010-09-07T14:59:39Z
dc.date.available2010-09-07T14:59:39Z
dc.date.created2010-09-07T14:59:39Z
dc.date.issued2002
dc.identifierSPECTROSCOPY LETTERS 35(5): 633-642
dc.identifier0038-7010
dc.identifierhttps://repositorio.uchile.cl/handle/2250/121032
dc.description.abstractElectron Spin Resonance spectra were obtained of the salicyliden-2-imino-5-nitropyrimidine (1(.-)), N,N-bis(5-nitro-salicyliden). ethylendiamine (2(.-)), 2-hydroxy-5-nitro-benziliden-5-iminoquinoline (3(.-)) anion I radicals produced by electro chemical reduction in DMSO. Hyperfine splitting constants were assigned by comparison with radical anions of similar structure and in some cases with the help of INDO method. For the (2(.-)) and (3(.-)) the substitutions in position meta affect greatly some proton coupling constants.
dc.languageen
dc.publisherMARCEL DEKKER INC
dc.subjectAnion radicals
dc.titleAn Electron Spin Resonance (ESR) investigation of potential ligands of inorganic interest with nitro substituents
dc.typeArtículo de revista


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