Artículo de revista
A convenient and highly productive aminohydroxylation protocol employing an osmium-diamine catalyst
Fecha
2006-09Registro en:
ADVANCED SYNTHESIS & CATALYSIS Volume: 348 Issue: 14 Pages: 1831-1835 Published: SEP 2006
1615-4150
Autor
Muñiz, Kilian
Almodovar, Iriux
Streuff, Jan
Nieger, Martin
Institución
Resumen
In situ generated osmium-diamine chelates from 2,3-diaminopropionic acid or diaminosuccinic acid represent efficient catalysts for the highly productive aminohydroxylation of alkenes. The reaction can be employed with various osmium salts and successful catalyst recycling was demonstrated for a representative example. The catalyst design derives from the general structural features of recently investigated osmium complexes from alkene diamination reactions