Chile
| Artículo de revista
pi-Strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers
dc.creator | Domingo, Luis R. | |
dc.creator | Pérez López, Patricia | |
dc.creator | Contreras Ramos, Renato | |
dc.date.accessioned | 2009-03-30T16:18:38Z | |
dc.date.available | 2009-03-30T16:18:38Z | |
dc.date.created | 2009-03-30T16:18:38Z | |
dc.date.issued | 2006-01-16 | |
dc.identifier | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY Issue: 2 Pages: 498-506 Published: JAN 16 2006 | |
dc.identifier | 1434-193X | |
dc.identifier | https://repositorio.uchile.cl/handle/2250/118788 | |
dc.description.abstract | Small cycloalkynes possess a pi-strain-induced electrophilicity related to the bending of the C-SP3-C-SP-C-SP bond angle. For cyclopentyne and benzyne, the electrophilicity index defined in the context of density functional theory gives a coherent rationale for the reactivity of these cycloalkynes, which may act as electrophiles in polar cycloaddition. reactions toward enol ethers. | |
dc.language | en | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.subject | POLARIZABLE CONTINUUM MODEL | |
dc.title | pi-Strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers | |
dc.type | Artículo de revista |