pi-Strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers

dc.creatorDomingo, Luis R.
dc.creatorPérez López, Patricia
dc.creatorContreras Ramos, Renato
dc.date.accessioned2009-03-30T16:18:38Z
dc.date.available2009-03-30T16:18:38Z
dc.date.created2009-03-30T16:18:38Z
dc.date.issued2006-01-16
dc.identifierEUROPEAN JOURNAL OF ORGANIC CHEMISTRY Issue: 2 Pages: 498-506 Published: JAN 16 2006
dc.identifier1434-193X
dc.identifierhttps://repositorio.uchile.cl/handle/2250/118788
dc.description.abstractSmall cycloalkynes possess a pi-strain-induced electrophilicity related to the bending of the C-SP3-C-SP-C-SP bond angle. For cyclopentyne and benzyne, the electrophilicity index defined in the context of density functional theory gives a coherent rationale for the reactivity of these cycloalkynes, which may act as electrophiles in polar cycloaddition. reactions toward enol ethers.
dc.languageen
dc.publisherWILEY-V C H VERLAG GMBH
dc.subjectPOLARIZABLE CONTINUUM MODEL
dc.titlepi-Strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers
dc.typeArtículo de revista


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