Industrial processes require materials with controlled properties, such as metals and alloys, which are obtained from a combination of metals and other species. The steel production in Brazil in 2013, e.g., was over 34 million tons. This importance reflects in standardized methods of analysis, such as ABNT and ASTM. Some of these methods are classical methods (gravimetric and volumetric) or instrumental and their choice depend on the analyte, the amount of sample, other interferences and cost. This text is a brief overview of recommended methods and those who bring innovations to metal analysis.649891009Chiaverini, V., (1978) Tecnologia Mecânica, , 2a. ed. McGraw-Hill do Brasil: São PauloMilan, M.T., Maluf, O., Spinelli, D., Bose-Filho, W.W., (2004) Metais: Uma Visão Objetiva, , Suprema: São CarlosCallister Jr., W.D., (2002) Ciência E Engenharia de Materiais: Uma Introdução, , 5a. ed. Livros Técnicos e Científicos S. A.: Rio de JaneiroSítio do Instituto Aço Brasil, , http://www.acobrasil.org.br/site/portugues/numeros/estatisticas.asp, Disponível em, Acesso em: 10 dezembro 2013Souza, S.A., (1989) Composição Química Dos Aços, , 1a. ed. Editora Edgard Blucher: São PauloTest Methods for Chemical Analysis of Carbon Steel, Low-alloy Steel, Silicon Electrical Steel, Ingot Iron, and Wrought Iron, , ASTM Standard E350 - 12, ASTM International. [CrossRef]Mendham, J., Denney, R.C., Barnes, J.D., Thomas, M.J.K., (2002) Análise Química Quantitativa, , 6a. ed. Livros Técnicos e Científicos S. A.: Rio de JaneiroSandell, E.B., Kolthoff, I.M., Lingane, J.J., A modified persulfate-arsenite method for manganese with special reference to steel analysis (1935) Industrial and Engineering Chemistry, Analytical Edition, 7, p. 256. , CrossRefSandell, E.B., Kolthoff, I.M., Lingane, J.J., Correction: A modified persulfate-arsenite method for manganese (1936) Industrial and Engineering Chemistry, Analytical Edition, 8, p. 73. , CrossRefNarayana, B., Bhat, N.G., Bhat, K.S., Nambiar, C.H.R., Ramachandra, B., Joseph, A., Selective complexometric determination of copper in ores and alloys using 2, 2'- bipyridyl as masking agent (2000) Microchemical Journal, 64, p. 221. , CrossRefNarayana, B., Joseph, A., Complexometric determination of zinc(ll) using 2, 2, -bipyridyl as selective masking agent (2000) Microchimica Acta, 134, p. 33. , CrossRefRamachandra, B., Narayana, B., Indirect complexometric determination of cadmium(ii) using 1, 10-phenanthroline as selective masking agent (1997) Microchimica Acta, 126, p. 223. , CrossRefKarthikeyan, J., Parameshwara, P., Shetty, A.N., Indirect complexometric determination of mercury(II) using 3-acetyl-2-thiohydantoin as a selective masking agent (2008) Indian Journal of Chemical Technology, 15, p. 493. , LinkSharpe, A.G., Wakefield, D.B., The basis of the selectivity of dimethylglyoxime as a reagent in gravimetric analysis (1957) Journal of the Chemical Society, p. 281. , CrossRefJunnila, P., Latvala, M., Matilainen, R., Tummavuori, J., Optimization of the gravimetric determination method of nickel as dimethylglyoximate for nickel raw materials (1999) Fresenius Journal of Analytical Chemistry, 365, p. 325. , CrossRefThyssen, J.P., Menné, T., Johansen, J.D., Nickel release from inexpensive jewelry and hair clasps purchased in an eu country - Are consumers sufficiently protected from nickel exposure? (2009) Science of the Total Environment, 407, p. 5315. , CrossRef, PubMedThyssen, J.P., Skare, L., Lundgren, L., Menné, T., Johansen, J.D., Maibach, H.I., Lidén, C., Sensitivity and specificity of the nickel spot (dimethylglyoxime) test (2010) Contact Dermatitis, 62, p. 279. , CrossRef, PubMedClaassen, A., Bastings, L., The determination of aluminium with 8-hydroxyquinoline. Part i. Precipitation in acetate-buffered solution (1967) Analyst, 92, p. 614. , CrossRefChalmers, R.A., Basit, M.A., A critical study of 8-hydroxyquinoline as a gravimetric reagent for aluminium (1967) Analyst, 92, p. 680. , CrossRefNan, Z., Gravimetric determination of tin with sodium cyclotetramethylenedithiocarbamate and its applications in metal analysis (1998) Talanta, 46, p. 1237. , CrossRefFeigl, F., Caldas, A., Detection of traces of iron (1957) Analytical Chemistry, 29, p. 580. , CrossRefTsai, S.-S.J., Jong, Y.-L., Spectrophotometric determination of iron and cobalt in super alloys (1989) Journal of the Chinese Chemical Society, 36, p. 11. , CrossRefFogg, A.G., Kumar, J.L., Burns, D.T., Spectrophotometric determination of molybdenum in steel with thiocyanate and tetraphenyl-arsonium chloride (1975) Analyst, 100, p. 311. , CrossRefKeshavan, B., Nagaraja, P., A rapid method for spectrophotometric determination of molybdenum in alloy steels (1985) Microchimica Acta, 86, p. 379. , CrossRefGervásio, A.P.G., Fortes, P.R., Meneses, S.R.P., Miranda, C.E.S., Zagatto, E.A.G., An improved flow-injection system for spectrophotometric determination of molybdenum and tungsten in tool steels (2006) Talanta, 69, p. 927. , CrossRef, PubMedSweetser, P.B., Briker, C.E., Spectrophotometric titrations with ethylenediaminetetraacetic acid (1953) Analytical Chemistry, 25, p. 253. , CrossRefFerreira, S.L.C., De Jesus, D.S., Cassella, R.J., Costa, A.C.S., De Carvalho, M.S., Santelli, R.E., An on-line solid phase extraction system using polyurethane foam for the spectrophotometric determination of nickel in silicates and alloys (1999) Analytica Chimica Acta, 378, p. 287. , CrossRefAmin, A.S., Saber, A.L., Mohammed, T.Y., Study on solid phase extraction and spectrophotometric determination of vanadium with 2, 3-dichloro-6-(2, 7-dihydroxy-1-naphthylazo)quinoxaline (2009) Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 73, p. 195. , CrossRef, PubMedFan, J., Sun, Y., Wang, J., Fan, M., An organic-reagent-free method for determination of chromium(vi) in steel alloys, sewage sludge and wastewater (2009) Analytica Chimica Acta, 640, p. 58. , CrossRef, PubMedHuseyinli, A.A., Alieva, R., Haciyeva, S., Guray, T., Spectrophotometry determination of aluminium and indium with 2, 2', 3, 4- Tetrahydroxy-3', 5'-disulphoazobenzene (2009) Journal of Hazardous Materials, 163, p. 1001. , CrossRef, PubMedBahram, M., Farhadi, K., Afkhami, A., Shokatynia, D., Arjmand, F., Simultaneous kinetic spectrophotometric determination of cu(II), co(II) and ni(II) using partial least squares (PLS) regression (2009) Central European Journal of Chemistry, 7, p. 375. , CrossRefBarreto, W.J., Barreto, S.R.G., Scarminio, I.S., Ishikawa, D.N., Soares, M.F., De Proença, M.V.B., Determination of ni(II) in metal alloys by spectrophotometry uv-vis using dopasemiquinone (2010) Química Nova, 33, p. 109. , CrossRefReddy, D.V., Chalapathi, P.V., Reddy, A.V., A rapid and direct sensitive spectrophotometric method for the determination of molybdenum(vi) using gallacetophenone phenylhydrazone with application to alloy steel samples (2011) E-Journal of Chemistry, 8, p. 1362. , CrossRefUysal, U.D., Huseyinli, A.A., Guray, T., Rapid direct spectrophotometry determination of zirconium(iv) in alloys with 2, 2, '3, 4-tetrahydroxy-3'-sulpho- 5'carboxyazobenzene reagent (2011) Journal of Scientific & Industrial Research, 70, p. 45. , LinkVarghese, A., George, L., Simultaneous first order derivative spectrophotometric determination of vanadium and zirconium in alloy steels and minerals (2012) Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 95, p. 46. , CrossRef, PubMedWelz, B., Sperling, M., (1999) Atomic Absorption Spectrometry, , 3a. ed. Wiley-VCH: WeinheimPandey, L.P., Ghose, A., Dasgupta, P., Rao, A.S., Determination of chromium in low-alloy steels by atomic-absorption spectrophotometry (1978) Talanta, 25, p. 482. , CrossRefOttaway, J.M., Pradhan, N.K., Determination of chromium in steel by atomic-absorption spectrometry with an air-acetylene flame (1973) Talanta, 20, p. 927. , CrossRefPurushottam, A., Naidu, P.P., Lal, S.S., Determination of molybdenum by atomic-absorption spectrophotometry (1972) Talanta, 19, p. 1193. , CrossRefTsai, S.-J.J., Bae, Y.-L., Flame atomic absorption spectrometric determination of magnesium in nickel-base alloys (1993) Analyst, 118, p. 301. , CrossRefMile, B., Rowlands, C.C., Jones, A.V., Single calibration method for the determination of lead in nickel alloys and steels by electrothermal atomic absorption spectrometry (1992) Journal of Analytical Atomic Spectrometry, 7, p. 1069. , CrossRefKrawczyk, M., Matusiewicz, H., Determination of gold by high-resolution continuum source atomic absorption spectrometry with chemical vapor generation (2013) Journal of the Brazilian Chemical Society, 24, p. 749. , CrossRefDessuy, M.B., De Jesus, R.M., Brandão, G.C., Ferreira, S.L.C., Vale, M.G.R., Welz, B., Fast sequential determination of antimony and lead in pewter alloys using high-resolution continuum source flame atomic absorption spectrometry (2013) Food Additives & Contaminants: Part a, 30, p. 202. , CrossRef, PubMedBorges, D.L.G., Curtius, A.J., Welz, B., Heitmann, U., Fundamentos da espectrometria de absorção atômica de alta resolução com fonte contínua (2005) Revista Analytica, 18, p. 58. , LinkVandecasteele, C., Block, C.B., (1997) Modern Methods for Trace Element Determination, , 1a. ed. John Wiley & Sons Ltd: ChichesterHoller, F.J., Skoog, D.A., Crouch, S.R., (2009) Princípios de Análise Instrumental, , 6a. ed. Bookman: Porto AlegreMerson, S., Evans, P., A high accuracy reference method for the determination of minor elements in steel by ICP-OES (2003) Journal of Analytical Atomic Spectrometry, 18, p. 372. , CrossRefWüstkamp, D., Kucharkowski, R., Broekaert, J.A.C., Highly accurate analysis of soft magnetic alloys by automated sample digestion and simultaneous ICP-OES (1996) Fresenius Journal of Analytical Chemistry, 355, p. 281. , CrossRefWüstkamp, D., Kucharkowski, R., Broekaert, J.A.C., Improved accuracy for the analysis of soft magnetic alloys by inductively-coupled plasma atomic emission spectrometry by using advanced standardization procedures (1996) Fresenius' Journal of Analytical Chemistry, 354, p. 879. , CrossRefHarmse, M.J., McCrindle, R.I., The determination of antimony in lead-antimony alloys using ICP-OES and internal standardization (2002) Journal of Analytical Atomic Spectrometry, 17, p. 1411. , CrossRefKovalev, I.A., Bogacheva, L.V., Tsysin, G.I., Formanovsky, A.A., Zolotov, T.A., FIA-FAAS system including on-line solid phase extraction for the determination of palladium, platinum and rhodium in alloys and ores (2000) Talanta, 52, p. 39. , CrossRefKarami, H., Mousavi, M.F., Yamini, Y., Shamsipur, M., On-line solid phase extraction and simultaneous determination of hafnium and zirconium by ICP-atomic emission spectroscopy (2006) Microchimica Acta, 154, p. 221. , CrossRefXu, Y., Wang, H., Wang, G., Wu, C., Zhou, J., Determination of trace amounts of rare-earth elements in clean steel by inductively coupled plasma optical emission spectrometry after removal of iron matrix with anion-exchange resin (2010) Applied Spectroscopy, 64, p. 543. , CrossRef, PubMedUemoto, M., Kobayashi, T., Sasaki, Y., Shimada, K., Izawa, K., Hasegawa, S.-I., Kobayashi, J.-I., Sakurai, F., Component analyses of silver brazing filler metals by inductively coupled plasma atomic emission spectrometry: A collaborative study for standardization (2011) Analytical Methods, 3, p. 1116. , CrossRefMedvedev, N.S., Gavrilyukov, N.N., Kukarin, V.F., Saprykin, A.I., Use of tandem calibration for analyzing steels and alloys by inductively coupled plasma atomic emission spectrometry (2013) Journal of Analytical Chemistry, 68, p. 616. , CrossRefRomanova, N.B., Pechishcheva, N.V., Shunyaev, K.Y., Titov, V.I., Gundobin, N.V., Determining low concentrations of zr, ce, la, and y in heat-resistant nickel alloys by inductively coupled plasma atomic emission (2012) Inorganic Materials, 48, p. 1315. , CrossRefBecker, J.S., Dietze, H.-J., Inorganic trace analysis by mass spectrometry (1998) Spectrochimica Acta Part B: Atomic Spectroscopy, 53, p. 1475. , CrossRefHu, J., Wang, H., Determination of trace elements in super alloy by ICP-MS Microchimica Acta 2001, 137, p. 149. , CrossRefMoor, C., Devos, W., Guecheva, M., Kobler, J., Inductively coupled plasma mass spectrometry: A versatile tool for a variety of different tasks (2000) Fresenius' Journal of Analytical Chemistry, 366, p. 159. , CrossRef, PubMedRecknagel, S., Richter, S., Reinholdsson, F., Pettersson, J., Gustavsson, I., An intercomparison study of analytical methods for the determination of magnesium in low alloy steel (2012) Steel Research International, 83, p. 146. , CrossRefDe Oliveira, E., Sample preparation for atomic spectroscopy: Evolution and future trends (2003) Journal of the Brazilian Chemical Society, 14, p. 174. , CrossRefJenkins, R., (1999) X-Ray Fluorescence, , 2a. ed. Wiley-Interscience: New YorkBrissey, R.M., Analysis of high temperature alloys by X-ray fluorescence (1953) Analytical Chemistry, 25, p. 190. , CrossRefMukhamedshina, N.M., Mirsagatova, A.A., Application of x-ray fluorescence for the analysis of some technological materials (2005) Applied Radiation and Isotopes, 63, p. 715. , CrossRef, PubMedHan, X.Y., Zhuo, S.J., Shen, R.X., Wang, P.L., Ji, A., Comparison of the quantitative results corrected by fundamental parameter method and difference calibration specimens in x-ray fluorescence spectrometry (2006) Journal of Quantitative Spectroscopy and Radiative Transfer, 97, p. 68. , CrossRefBelyaeva, E.E., Ershov, A.V., Mashin, A.I., Mashin, N.I., Rudnevskii, N.K., X-ray fluorescence analysis of fe-n-mo systems (1998) Journal of Analytical Chemistry, 53, p. 561Zawisza, B., Determination of beryllium by using x-ray fluorescence spectrometry (2008) Analytical Chemistry, 80, p. 1696. , CrossRef, PubMedZawisza, B., Sitko, R., Indirect determination of beryllium by x-ray fluorescence spectrometry via a complex with cobalt (2008) Journal of Analytical Atomic Spectrometry, 23, p. 1628. , CrossRefBarrea, R.A., Mainardi, R.T., Standardless XRF analysis of stainless-steel samples (1998) X-Ray Spectrometry, 27, p. 111. , CrossRefTiwari, M.K., Singh, A.K., Sawhney, K.J.S., Analysis of stainless steel samples by energy dispersive X-ray fluorescence (EDXRF) spectrometry (2001) Bulletin of Materials Science, 24, p. 633. , CrossRefReisel, J., Geyer, J., Flock, J., Sommer, D., Speciation of inclusions and precipitates in steel by means of XRF and LEEIXS (2003) X-Ray Spectrometry, 32, p. 29. , CrossRefPitarch, A., Queralt, I., Energy dispersive x-ray fluorescence analysis of ancient coins: The case of greek silver drachmae from the emporion site in Spain (2010) Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 268, p. 1682. , CrossRefRodrigues, M., Schreiner, M., Melcher, M., Guerra, M., Salomon, J., Radtke, M., Alram, M., Schindel, N., Characterization of the silver coins of the hoard of beçin by x-ray based methods (2011) Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 269, p. 3041. , CrossRefPitarch, A., Queralt, I., Alvarez-Perez, A., Analysis of catalonian silver coins from the spanish war of independence period (1808-1814) by energy dispersive x-ray fluorescence (2011) Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 269, p. 308. , CrossRefGliozzo, E., Arletti, R., Cartechini, L., Imberti, S., Kockelmann, W.A., Memmi, I., Rinaldi, R., Tykot, R.H., Non-invasive chemical and phase analysis of roman bronze artefacts from thamusida (morocco) (2010) Applied Radiation and Isotopes, 68, p. 2246. , CrossRef, PubMedTissot, I., Tissot, M., Manso, M., Alves, L.C., Barreiros, M.A., Marcelo, T., Carvalho, M.L., Guerra, M.F., The earrings of pancas treasure: Analytical study by x-ray based techniques - A first approach (2013) Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 306, p. 236. , CrossRefBosco, G.L., Development and application of portable, hand-held x-ray fluorescence spectrometers (2013) TrAC Trends in Analytical Chemistry, 45, p. 121. , CrossRefDa-Col, J.A., Bueno, M.I.M.S., Melquiades, F.L., Nondestructive determination of allergenic and toxics elements in jewelry: A comparison of benchtop and portable energy dispersive X-ray fluorescence spectrometers (2014) Journal of the Brazilian Chemical Society, 25, p. 853. , CrossRefRakotondrajoa, A., Buzanich, G., Radtke, M., Reinholz, U., Riesemeier, H., Vincze, L., Raboanary, R., Improvement of PLS regression-based XRF spectroscopy quantification using multiple step procedure and monte carlo simulation (2013) X-Ray Spectrometry, 42, p. 183. , CrossRefZaidi, J.H., Waheed, S., Ahmed, S., Determination of trace impurities in nickel-based alloy using neutron activation analysis (1999) Journal of Radioanalytical and Nuclear Chemistry, 242, p. 259. , CrossRefZaidi, J.H., Waheed, S., Ahmed, S., Determination of trace impurities in iron-based alloy using neutron activation analysis (2000) Radiochimica Acta, 88, p. 233. , CrossRefPolkowska-Motrenko, H., Chajduk, E., Danko, B., Instrumental neutron activation analysis (INAA) for steel analysis and certification (2011) Nukleonika, 56, p. 311. , LinkAcharya, R., Kolay, S., Reddy, A.V.R., Determination of nickel in finished product alloys by instrumental neutron activation analysis and spectrophotometry (2012) Journal of Radioanalytical and Nuclear Chemistry, 294, p. 309. , CrossRefKhalid, N., Wasim, M., Lodhi, N.A., Arif, M., Performance evaluation of ko-instrumental neutron activation analysis and flame atomic absorption spectrophotometry in the characterization of various types of alloys (2013) Journal of Radioanalytical and Nuclear Chemistry, 297, p. 153. , CrossRefMoreira, E.G., Vasconcellos, M.B.A., Saiki, M., Instrumental neutron activation analysis applied to the determination of the chemical composition of metallic materials with study of interferences (2005) Journal of Radioanalytical and Nuclear Chemistry, 264, p. 45. , CrossRefCincu, E., Manea, I., Manu, V., Bardos, D., Sima, O., Gustavsson, I., Vermaercke, P., Polkowska-Motrenko, H., Comparative performance of inaa and other spectroscopy techniques in the elemental analysis of stainless steel materials (2007) Journal of Radioanalytical and Nuclear Chemistry, 274, p. 199. , CrossRefPasquini, C., Cortez, J., Silva, L.M.C., Gonzaga, F.B., Laser induced breakdown spectroscopy (2007) Journal of the Brazilian Chemical Society, 18, p. 463. , CrossRefNoll, R., Bette, H., Brysch, A., Kraushaar, M., Mönch, I., Peter, L., Sturm, V., Laser-induced breakdown spectrometry - Applications for production control and quality assurance in the steel industry (2001) Spectrochimica Acta Part B: Atomic Spectroscopy, 56, p. 637. , CrossRefDong, F.-Z., Chen, X.-L., Wang, Q., Sun, L.-X., Yu, H.-B., Liang, Y.-X., Wang, J.-G., Lu, J.-D., Recent progress on the application of libs for metallurgical online analysis in China (2012) Frontiers of Physics, 7, p. 679. , CrossRefElhassan, A., Giakoumaki, A., Anglos, D., Ingo, G.M., Robbiola, L., Harith, M.A., Nanosecond and femtosecond laser induced breakdown spectroscopic analysis of bronze alloys (2008) Spectrochimica Acta Part B: Atomic Spectroscopy, 63, p. 504. , CrossRefWindom, B.C., Hahn, D.W., Laser ablation-laser induced breakdown spectroscopy (LA-LIBS): A means for overcoming matrix effects leading to improved analyte response (2009) Journal of Analytical Atomic Spectrometry, 24, p. 1665. , CrossRefSorrentino, F., Carelli, G., Francesconi, F., Francesconi, M., Marsili, P., Cristoforetti, G., Legnaioli, S., Tognoni, E., Fast analysis of complex metallic alloys by double-pulse time-integrated laser-induced breakdown spectroscopy (2009) Spectrochimica Acta Part B: Atomic Spectroscopy, 64, p. 1068. , CrossRefShah, M.L., Pulhani, A.K., Gupta, G.P., Suri, B.M., Quantitative elemental analysis of steel using calibration-free laser-induced breakdown spectroscopy (2012) Applied Optics, 51, p. 4612. , CrossRef, PubMedGurell, J., Bengston, A., Falkenström, M., Hansson, B.A.M., Laser induced breakdown spectroscopy for fast elemental analysis and sorting of metallic scrap pieces using certified reference materials (2012) Spectrochimica Acta Part B: Atomic Spectroscopy, 74-75, p. 46. , CrossRefHo, S.K., A minimally destructive multi-element sensing technique for metal alloys by laser-induced breakdown spectroscopy (2012) Japanese Journal of Applied Physics, 51, p. 082401. , CrossRefKhater, M.A., Laser-induced breakdown spectroscopy for light elements detection in steel: State of the art (2013) Spectrochimica Acta Part B: Atomic Spectroscopy, 81, p. 1. , CrossRefLuo, W., Tang, J., Gao, C., Wang, H., Zhao, W., Spectroscopic analysis of element concentrations in aluminum alloy using nanosecond laser-induced breakdown spectroscopy (2010) Physica Scripta, 81, p. 065302. , CrossRefGoueguel, C., Laville, S., Vidal, F., Sabsabi, M., Chaker, M., Investigation of resonance-enhanced laser-induced breakdown spectroscopy for analysis of aluminium alloys (2010) Journal of Analytical Atomic Spectrometry, 25, p. 635. , CrossRefRifai, K., Vidal, F., Chaker, M., Sabsabi, M., Resonant laser-induced breakdown spectroscopy (RLIBS) analysis of traces through selective excitation of aluminum in aluminum alloys (2013) Journal of Analytical Atomic Spectrometry, 28, p. 388. , CrossRefGoueguel, C., Laville, S., Vidal, F., Chaker, M., Sabsabi, M., Resonant laser-induced breakdown spectroscopy for analysis of lead traces in copper alloys (2011) Journal of Analytical Atomic Spectrometry, 26, p. 2452. , CrossRefShaltout, A.A., Abdel-Aal, M.S., Mostafa, N.Y., The validity of commercial LIBS for quantitative analysis of brass alloy - comparison of WDXRF and AAS (2011) Journal of Applied Spectroscopy, 78, p. 594. , CrossRefZhu, D., Wang, X., Ni, X., Chen, J., Lu, J., Determination of aluminum in nickel-based superalloys by using laser-induced breakdown spectroscopy (2011) Plasma Science and Technology, 13, p. 486. , CrossRefGupta, G.P., Suri, B.M., Verma, A., Sundararaman, M., Unnikrishnan, V.K., Alti, K., Kartha, V.B., Santhosh, C., Quantitative elemental analysis of nickel alloys using calibration-based laser-induced breakdown spectroscopy (2011) Journal of Alloys and Compounds, 509, p. 3740. , CrossRefArafat, A., Na'es, M., Kantarelou, V., Haddad, N., Giakoumaki, A., Argyropoulos, V., Anglos, D., Karydas, A.-G., Combined in situ micro-XRF, LIBS and SEM-EDS analysis of base metal and corrosion products for islamic copper alloyed artefacts from umm qais museum, Jordan (2013) Journal of Cultural Heritage, 14, p. 261. , CrossRefStipe, C.B., Hensley, B.D., Boersema, J.L., Buckley, S.G., Laser-induced breakdown spectroscopy of steel: A comparison of univariate and multivariate calibration methods (2010) Applied Spectroscopy, 64, p. 154. , CrossRef, PubMedContreras, U., Meneses-Nava, M.A., Torres-Armenta, D., Robles-Camacho, J., Barbosa-Garcia, O., Identificación de aceros por espectroscopia de rompimiento inducido por láser (LIBS) y análisis de componentes principales (2012) Revista Mexicana de Física, 58, p. 184. , LinkGoode, S.R., Morgan, S.L., Hoskins, R., Oxsher, A., Identifying alloys by laser-induced breakdown spectroscopy with a time-resolved high resolution echelle spectrometer (2000) Journal of Analytical Atomic Spectrometry, 15, p. 1133. , CrossRefJurado-López, A., Luque-De-Castro, M.D., Chemometric approach to laser-induced breakdown analysis of gold alloys (2003) Applied Spectroscopy, 57, p. 349. , CrossRef, PubMedDoucet, F.R., Belliveau, T.F., Fortier, J.-L., Hubert, J., Use of chemometrics and laser-induced breakdown spectroscopy for quantitative analysis of major and minor elements in aluminum alloys (2007) Applied Spectroscopy, 61, p. 327. , CrossRef, PubMedInakollu, P., Philip, T., Rai, A.K., Yueh, F.-Y., Singh, J.P., A comparative study of laser induced breakdown spectroscopy analysis for element concentrations in aluminum alloy using artificial neural networks and calibration methods (2009) Spectrochimica Acta Part B: Atomic Spectroscopy, 64, p. 99. , CrossRefHoffmann, E., Lüdke, C., Skole, J., Stephanowitz, H., Wollbrandt, J., Becker, W., New methodical and instrumental developments in laser ablation inductively coupled plasma mass spectrometry (2002) Spectrochimica Acta Part B: Atomic Spectroscopy, 57, p. 1535. , CrossRefSarah, G., Gratuze, B., Barrandon, J.-N., Application of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for the investigation of ancient silver coins Journal of Analytical Atomic Spectrometry, 22, pp. 1163-2007. , CrossRefKarasev, A.V., Suito, H., Inoue, R., Application of laser ablation ICP mass spectrometry for analysis of oxide particles on cross section of alloys and steels (2011) ISIJ International, 51, p. 2042. , CrossRefShibukawa, M., Yamazaki, A., Saito, S., Saitoh, K., Determination of trace amount of cobalt in a steel sample by two-dimensional on-line redox derivatization liquid chromatography (2012) ISIJ International, 52, p. 1622. , CrossRefGonzález, J., Liu, C., Mao, X., Russo, R.E., Uv-femtosecond laser ablation-ICP-MS for analysis of alloy samples (2004) Journal of Analytical Atomic Spectrometry, 19, p. 1165. , CrossRefLatkoczy, C., Müller, Y., Schmutz, P., Güther, D., Quantitative element mapping of mg alloys by laser ablation ICP-MS and EPMA (2005) Applied Surface Science, 252, p. 127. , CrossRefHu, J., Han, M., Yuan, L., Wang, H., Original position statistic distribution analysis of trace element segregation in nickel-base super alloy by LA-ICP-MS (2012) ISIJ International, 52, p. 2055. , CrossRefUsero, R., Coedo, A.G., Dorado, M.T., Padilla, I., Influence of different metal matrices on manganese signal response in laser ablation inductively coupled plasma-mass spectrometry (2009) Applied Spectroscopy, 63, p. 859. , CrossRef, PubMedLatkoczy, C., Ghislain, T., Simultaneous LIBS and LA-ICP-MS analysis of industrial samples (2006) Journal of Analytical Atomic Spectrometry, 21, p. 1152. , CrossRef