Artículos de revistas
Valorization Of Sugarcane Biorefinery Residues Using Supercritical Water Gasification: A Case Study And Perspectives
Registro en:
Journal Of Supercritical Fluids. Elsevier, v. 96, n. , p. 133 - 143, 2015.
8968446
10.1016/j.supflu.2014.09.009
2-s2.0-84918838472
Autor
Albarelli J.Q.
Mian A.
Santos D.T.
Ensinas A.V.
Marechal F.
Meireles M.A.A.
Institución
Resumen
The present study evaluates the use of supercritical fluid technology, particularly supercritical water gasification (SCWG), to add value to residues from a sugarcane biorefinery that produces first and second generation ethanol. This case study aims at elucidating how process system engineering tools such as thermal process integration, life cycle analysis, economic evaluation and multi-objective optimization can contribute to minimizing some future challenges of the industrial implementation of supercritical fluid-based technologies, which were discussed in the Workshop on Supercritical Fluids and Energy - SFE'13. In addition, this case study exposes future perspectives in terms of the requirements to further develop this field. The optimized solutions of the evaluated case showed that the SCWG process increases the overall efficiency of the process in terms of energy and carbon fixation. It decreases the CO2 equivalent emissions and it leads to a thermally self-sufficient process. The economic analysis showed a high investment cost but a feasibility of using the current market prices for the produced fuels and electricity. 96
133 143 Hofsetz, K., Silva, M.A., Brazilian sugarcane bagasse: Energy and non-energy consumption (2012) Biomass and Bioenergy, 46, pp. 564-573 Albarelli, J.Q., Ensinas, A.V., Silva, M.A., Product diversification to enhance economic viability of second generation ethanol production in Brazil: The case of the sugar and ethanol joint production (2014) Chemical Engineering Research and Design, 92, pp. 1470-1481 Stephen, J.D., Mabee, W.E., Saddler, J.N., Will second-generation ethanol be able to compete with first-generation ethanol? Opportunities for cost reduction (2012) Biofuels, Bioproducts and Biorefining, 6, pp. 159-176 Clements, L.D., Van Dyne, D.L., The lignocellulosic biorefinery: A strategy for returning to a sustainable source of fuels and industrial organic chemicals (2006) Biorefineries - Industrial Processes and Products: Status Quo and Future Directions, pp. 115-128. , B. Kamm, P.R. Gruber, M. Kamm, Wiley-VCH Weinheim Demirbas, A., Biorefineries: Current activities and future developments (2009) Energy Conversion and Management, 50, pp. 2782-2801 Kamm, B., Introduction of biomass and biorefineries (2013) The Role of Green Chemistry in Biomass Processing and Conversion, pp. 1-26. , H. Xie, N. Gathergood, John Wiley & Sons, Inc. New Jersey Ensinas, A.V., Codina, V., Maréchal, F., Albarelli, J.Q., Silva, M.A., Thermo-economic optimization of integrated first and second generation sugarcane ethanol plant (2013) Chemical Engineering Transactions, 35, pp. 523-528 Kang, S., Li, X., Fan, J., Chang, J., Hydrothermal conversion of lignin: A review (2013) Renewable and Sustainable Energy Reviews, 27, pp. 546-558 Sato, T., Furusawa, T., Ishiyama, Y., Sugito, H., Miura, Y., Sato, M., Suzuki, N., Itoh, N., Effect of water density on the gasification of lignin with magnesium oxide supported nickel catalysts in supercritical water (2006) Industrial & Engineering Chemistry Research, 45, pp. 615-622 Goodwin, A.K., Rorrer, G.L., Modeling of supercritical water gasification of xylose to hydrogen-rich gas in a hastelloy microchannel reactor (2011) Industrial & Engineering Chemistry Research, 50, pp. 7172-7182 Loppinet-Serani, A., Reverte, C., Cansell, F., Aymonier, C., Supercritical water biomass gasification process as a successful solution to valorize wine distillery wastewaters (2013) ACS Sustainable Chemistry & Engineering, 1, pp. 110-117 Kruse, A., Hydrothermal biomass gasification (2009) J. Supercritical Fluids, 47, pp. 391-399 Ye, X.P., Cheng, L., Ma, H., Bujanovic, B., Goundalkar, M.J., Amidon, T.E., Biorefinery with water (2013) The Role of Green Chemistry in Biomass Processing and Conversion, pp. 135-180. , H. Xie, N. Gathergood, John Wiley & Sons, Inc. New Jersey Zöhrer, H., Vogel, F., Hydrothermal catalytic gasification of fermentation residues from a biogas plant (2013) Biomass and Bioenergy, 53, pp. 138-148 (2006) Environmental Management - Life Cycle Assessment - Principles and Framework, , http://www.iso.org/, Iso 14040 International Standard Available from (2006) Environmental Management - Life Cycle Assessment - Requirements and Guidelines, , http://www.iso.org/, Iso 14044 International Standard Available from Gerber, L., Gassner, M., Maréchal, F., Systematic integration of LCA in process systems design: Application to combined fuel and electricity production from lignocellulosic biomass (2011) Computers and Chemical Engineering, 35, pp. 1265-1280 (2013) Workshop on Supercritical Fluids and Energy - SFE'13, , http://lasefi.com.br/sfe13/, Campinas, Brazil, 8-11 December 2013 Available from (2010) Aspen Plus, V. 7.2, , http://www.aspentech.com/, Available from Rein, P., (2007) Cane Sugar Engineering, , Verlag Dr. Albert Bartens KG Berlin Carrasco, C., Baudel, H.M., Sendelius, J., Modig, T., Roslander, C., Galbe, M., Hahn-Hägerdal, B., Lidén, G., SO2 catalyzed steam pretreatment and fermentation of enzymatically hydrolyzed sugarcane bagasse (2010) Enzyme and Microbial Technology, 46, pp. 64-73 Arantes, V., Saddler, J.N., Cellulose accessibility limits the effectiveness of minimum cellulase loading on the efficient hydrolysis of pretreated lignocellulosic substrates (2011) Biotechnology for Biofuels, 4, pp. 1-16 (2013) Belsim Vali 4.7.0.0, , http://www.belsim.com/, Available from Gassner, M., Vogel, F., Heyen, G., Maréchal, F., Optimal process design for the polygeneration of SNG, power and heat by hydrothermal gasification of waste biomass: Thermo-economic process modelling and integration (2011) Energy & Environmental Science, 4, pp. 1726-1741 Waldner, M.H., (2007) Catalytic Hydrothermal Gasification of Biomass for the Production of Synthetic Natural Gas, , (Ph.D. thesis) Eidgenössische Technische Hochschule Zürich (ETH) Zürich, Switzerland Bolliger, R., (2010) Méthodologie de la Synthèse des Systems Énergétiques Industriels, , (Ph.D. thesis) École Polytechnique Fédérale de Lausanne (EPFL) Lausanne, Switzerland Molyneaux, A., Leyland, G., Favrat, D., Environomic multi-objective optimisation of a district heating network considering centralized and decentralized heat pumps (2010) Energy, 35, pp. 751-758 Gassner, M., Maréchal, F., Methodology for the optimal thermo-economic, multi-objective design of thermochemical fuel production from biomass (2009) Computers & Chemical Engineering, 33, pp. 769-781 (2013) OSMOSE Platform: A Tool for the Design and Analysis of Integrated Energy Systems, , http://leni.epfl.ch/osmose Linnhoff, B., (1982) User Guide on Process Integration for the Efficient Use of Energy, , 1st ed. IChemE Rugby Turton, R., (2009) Analysis, Synthesis, and Design of Chemical Processes, , 3rd ed. Prentice-Hall Upper Saddle River Ulrich, G., Vasudevan, P., (2003) A Guide to Chemical Engineering Process Design and Economics: A Practical Guide, , 2nd ed. CRC Boca Raton Gerber, L., (2012) Integration of Life Cycle Assessment in the Conceptual Design of Renewable Energy Conversion Systems, , (Ph.D. thesis) École Polytechnique Fédérale de Lausanne (EPFL) Lausanne, Switzerland (2010) Implementation of Life Cycle Impact Assessment Methods, , http://www.ecoinvent.org/fileadmin/documents/en/03_LCIA-Implementation-v2.2.pdf, Ecoinventreport St. Gallen Available from: (accessed 01.06.13) (2013) Economic Indicators. Marshall & Swift Equipment Cost Index, , https://www.marshallswift.com/p-30-marshall-valuation-service.aspx (2012) UNICA Preço-teto de Leilão de Energia Desencoraja Investimentos em Bioeletricidade, , http://www.unica.com.br/noticias/show.asp%3FnwsCode=%7B3985304E-7262-4ED3-8EDE-D85A38934B72%7D Humbird, D., Davis, R., Tao, L., Kinchin, C., Hsu, D., Aden, A., (2011) Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol. Technical Report. NREL/TP-5100-47764 Elia Neto, A., (2009) Manual de Conservação e Reuso de Água Na Agroindústria Sucroenergética, , Agência Nacional de Águas (ANA) Brasilia Klein-Marcuschamer, D., Oleskowicz-Popiel, P., Simmons, B.A., Blanch, H.W., The challenge of enzyme cost in the production of lignocellulosic biofuels (2012) Biotechnology and Bioengineering, 109, pp. 1083-1087