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Conferring specificity in redox pathways by enzymatic thiol/disulfide exchange reactions
(Taylor & Francis Ltd, 2016-02-01)
Thiol-disulfide exchange reactions are highly reversible, displaying nucleophilic substitutions mechanism (S(N)2 type). For aliphatic, low molecular thiols, these reactions are slow, but can attain million times faster ...
Thiol oxidation by nitrosative stress: Cellular localization in human spermatozoa
(Informa Healthcare, 2016-09)
Peroxynitrite is a highly reactive nitrogen species and when it is generated at high levels it causes nitrosative stress, an important cause of impaired sperm function. High levels of peroxynitrite have been shown to ...
Thiol-methacrylate networks and its application in novel hydrogels
(Nova Science Publishers, 2019)
Thiol-ene systems have attracted considerable recent interest because they display efficient, versatile and selective “click” reactions. In this study, thiol-methacrylate networks based on a tetrafunctional thiol (PTMP) ...
Chemisorption on thiol-silicas: Divalent cations as a function of pH and primary amines on thiol-mercury adsorbed
(Academic Press IncSan DiegoEUA, 1997)
Thiol-independent activity of a cholesterol-binding enterohemolysin produced by enteropathogenic Escherichia coli
(Associação Brasileira de Divulgação Científica, 2003)
Mechanism for the SNAr reaction of atrazine with endogenous thiols: experimental and theoretical study
(Royal Society of Chemistry, 2017)
Reaction mechanism in aromatic nucleophilic substitution reactions is discussed using kinetic study
complemented with quantum chemical calculations. The model system is the reaction of a series of
biothiols toward atrazine ...
Mechanism for the SNAr reaction of atrazine with endogenous thiols: experimental and theoretical study
(Royal Society of Chemistry, 2017)
Reaction mechanism in aromatic nucleophilic substitution reactions is discussed using kinetic study
complemented with quantum chemical calculations. The model system is the reaction of a series of
biothiols toward atrazine ...
Aromatic and aliphatic thiol self-assembled monolayers on Au: Anchoring and delivering copper species
(2011)
The immobilization of dinuclear copper(II) acetate complexes (Cu2(CH3COO)4·2H2O) on self-assembled monolayers (SAMs) of different aliphatic and aromatic thiols with oxygen and nitrogen donors at the end group is investigated ...
From NMP to RAFT and thiol-ene chemistry by in situ functionalization of nitroxide chain ends
(Wiley VCH Verlag, 2012-08-25)
A straightforward, novel strategy based on the in situ functionalization of polymers prepared by nitroxide-mediated polymerization (NMP), for the use as an extension toward block copolymers and post-polymerization ...