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Changes in the SNAr reaction mechanism brought about by preferential solvation
(Royal Soc Chemistry, 2015)
We herein report an experimental and theoretical study on preferential solvation effects for the reactions of 1-fluoro and 1-chloro-2,4-dinitrobenzene towards morpholine in acetonitrile, water and mixtures of them of varying ...
Substituent effects in the C-13 NMR chemical shifts of alpha-mono-substituted acetonitriles
(Pergamon-elsevier Science LtdOxfordInglaterra, 2007)
Acetone as a greener alternative to acetonitrile in liquid chromatographic fingerprinting
(Wiley-Blackwell, 2015-05-01)
A considerable amount of chemical waste from liquid chromatography analysis is generated worldwide. Acetonitrile is the most employed solvent in liquid chromatography analyses since it exhibits favorable physicochemical ...
Trans-kinetic effects in ligand substitution processes of ruthenium polypyridyl complexes
(Elsevier Science, 2018-12)
A concerted mechanism is disclosed when studying trans-kinetic effects in substitution processes of complexes of formula [Ru(trpy)(4,4′-(X) 2 -bpy)(H 2 O)] 2+ , with trpy = 2,2′:6′,2″-terpyridine, bpy = 2,2′-bipyridine and ...
Elimination Of The Artefact Peaks In Capillary Electrophoresis Determination Of Glutamate By Using Organic Solvents In Sample Preparation
(WILEY-V C H VERLAG GMBHWEINHEIM, 2015)
Electrochemical characterization of hydroquinone derivatives with different substituents in acetonitrile
(Royal Soc Chemistry, 2015)
The effect of carbonyl groups in the ortho position with respect to a hydroxyl group on the electrochemical oxidation of hydroquinones in acetonitrile is studied. The electrochemical response of hydroquinone on a glassy ...
Radical Ions of 3-Styryl-quinoxalin-2-one derivatives studied by pulse radiolysis in organic solvents
(Amer Chemical SOC, 2018)
The absorption-spectral and kinetic behaviors of radical ions and neutral hydrogenated radicals of seven 3-styryl-quinoxalin-2(1 H)-one (3-SQ) derivatives, one without substituents in the styryl moiety, four others with ...
Acetone as a greener alternative to acetonitrile in liquid chromatographic fingerprinting
(Wiley-Blackwell, 2015)
Acetone as a greener alternative to acetonitrile in liquid chromatographic fingerprinting
(Wiley-Blackwell, 2015)
Changes in the SNAr reaction mechanism brought about by preferential solvation
(Royal Society of Chemistry, 2015)
We herein report an experimental and theoretical study on preferential solvation effects for the reactions of 1-fluoro and 1-chloro-2,4-dinitrobenzene towards morpholine in acetonitrile, water and mixtures of them of varying ...