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Determination of chemical rate constants in singlet molecular oxygen reaction by using 1,4-dimethylnaphthalene endoperoxide
(2002)
Thermal decomposition of 1,4-dimethylnaphthalene endoperoxide (DMNE) as a source of singlet oxygen was used to measure chemical rate constants, k(R), for reactions between singlet oxygen, O-2((1)Delta(g)), and various ...
A quasiclassical trajectory study of the OH plus SO reaction: The role of rotational energy
(AMER INST PHYSICS, 2010)
A full dimensional quasiclassical trajectory study of the OH+SO reaction is presented with the aim of investigating the role of the reactants rotational energy in the reactivity. Different energetic combinations with one ...
Surface spectators and their role in relationships between activity and selectivity of the oxygen reduction reaction in acid environments
(2015-08-12)
Abstract We use the rotating ring disk (RRDE) method to study activity-selectivity relationships for the oxygen reduction reaction (ORR) on Pt(111) modified by various surface coverages of adsorbed CN<inf>ad</inf> ...
Driving the Oxygen Evolution Reaction by Nonlinear Cooperativity in Bimetallic Coordination Catalysts
(American Chemical Society, 2016-03)
Developing efficient catalysts for electrolysis, in particular for the oxygen evolution in the anodic half cell reaction, is an important challenge in energy conversion technologies. By taking inspiration from the catalytic ...
A non-singlet oxygen mediated reaction photoinduced by phenalenone, a universal reference for singlet oxygen sensitization
(Royal Society of Chemistry, 2014-02)
Photosensitized oxidations involve the generation of radicals (type I mechanism) and/or the production of singlet molecular oxygen (1O2) (type II mechanism). Phenalenone (PN) is one of the well-known type II photosensitizers ...