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Formic Acid Electrooxidation on Platinum, Resolution of the Kinetic Mechanism in Steady State and Evaluation of the Kinetic Constants
(Wiley Blackwell Publishing, Inc, 2018-09)
A kinetic mechanism recently proposed for the formic acid oxidation (FAO) on platinum in acid solutions was analytically solved in order to verify its capability to correlate experimental measurements in steady state ...
Cure kinetics of diglycidylether of bisphenol A– ethylenediamine revisited using a mechanistic model
(John Wiley & Sons Inc, 2001-09-14)
The polymerization kinetics of the reaction between diglycidylether of bisphenol A (DGEBA) and ethylenediamine (EDA) was analyzed, using dynamic scanning calorimetry, in both isothermal and programmed heating-rate modes. ...
Diffusion controlled LHHW kinetics. Simultaneous determination of chemical kinetic and equilibrium adsorption constants by using the Weisz-Prater approach
(Pergamon-Elsevier Science Ltd, 2017-11)
A method to simultaneously determine the chemical kinetics (kCT) and Langmuir’s adsorption equilibrium (KL) constants in porous catalyst particles where chemical reactions following Langmuir-Hinshel wood-Hougen-Watson ...
Isoconversional kinetics of vaporization of nanoconfined liquids
(Elsevier B.V., 2021-04-01)
Isoconversional kinetic analysis is applied to thermogravimetry data on vaporization of n-decane and dimethyl sulfoxide from alumina nanopores and bulk. For bulk vaporization, the isoconversional activation energy is ...
Kinetic studies of the photocatalytic degradation of Tartrazine
(Planta Piloto de Ingeniería Química, 2012-02)
Kinetic studies of the photocatalytic degradation of tartrazine are carried out in a batch stirred reactor built in quartz at laboratory scale using TiO2 as catalyst and irradiating the photoreactor with ultraviolet light. ...
DNA hybridization mechanism in an interfacial environment: What hides beneath first order k (s(-1)) kinetic constant?
(Elsevier B.V. Sa, 2012-08-01)
The scientific question addressed in this work is: what hides beneath first order kinetic constant k (s(-1)) measured for hybridization of a DNA target on a biosensor surface. Kinetics hybridization curves were established ...
DNA hybridization mechanism in an interfacial environment: What hides beneath first order k (s(-1)) kinetic constant?
(Elsevier B.V. Sa, 2012-08-01)
The scientific question addressed in this work is: what hides beneath first order kinetic constant k (s(-1)) measured for hybridization of a DNA target on a biosensor surface. Kinetics hybridization curves were established ...
Cure kinetics and shrinkage model for epoxy-amine systems
(Elsevier, 2005-12)
Manufacture of most of epoxy resins implies that cure needs to be carried out under pressure. Due to the significance of knowing the influence of the pressure factor in cure kinetics, cure shrinkage of a stoichiometric ...
Modeling the sorption kinetic of metsulfuron-methyl on Andisols and Ultisols volcanic ash-derived soils: Kinetics parameters and solute transport mechanisms
(2010)
Metsulfuron-methyl sorption kinetic was studied in Andisol and Ultisol soils in view of their distinctive physical and chemical properties: acidic pH and variable surface charge. Different kinetic models were applied to ...