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Thermal decomposition reaction in ethanol solution of deuterated acetone cyclic diperoxide and acetone diperoxide. Secondary inverse isotopic effect
(Sociedade Brasileira de Química, 2017-05)
The characterization by mass spectrometry and the kinetic study of the thermal decomposition reaction of deuterated acetone diperoxide (dACDP) was studied in ethanol in the 140-165 °C temperature range. The comparison with ...
Theoretical study of the gas-phase thermolysis of 3-methyl-1,2,4,5- tetroxane
(Springer Verlag, 2014)
Thermal Decomposition Reaction of Pinacolone Diperoxide: its Use as Radical Initiator in the Styrene Polymerization
(Springer, 2017-09)
Some commercial vinyl polymers such as polystyrene, polymethylmethacrylate and polyvinyl chloride have been synthetized through last years using new initiators, for example those with multiple active sites. Multifunctional ...
Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography
(Gupta Publications, 2020-02)
Gas phase thermolysis reaction of glutaraldehyde acid diperoxide (3,6-dibutanoic -1,2,4,5-tetroxane,DPAG) was performed in an injection chamber of a gas chromatograph as a constant time thermal flow reactor, has been applied ...
Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
(Science Journal of Pure and Applied Chemistry, 2015)
The thermal decomposition reaction of Cyclic
GlutaraldehydeDiperoxide (3,6-dibutanal-1,2,4,5-tetroxane) in
solution of methanol in the temperature range of 130.0-166.0°C and
initial concentration of 1.69 x10-3 mol/L, ...
Kinetic of the thermal decomposition of disubstituted tetroxanes
(India, 2016-10)
The thermal decomposition of diphenyl diperoxide (DFT) and dibutanal diperoxide (DPG) were investigated over the temperature range 130 to 166°C. They were found to be first order with a high degree of conversion (60%). ...