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Thermodynamic consistency of experimental VLE data for asymmetric binary mixtures at high pressures
(Elsevier Science, 2010-06)
A thermodynamic consistency of isothermal vapor-liquid equilibrium data for 9 non-polar and 8 polar binary asymmetric mixtures at high pressures has been evaluated. A method based on the isothermal Gibbs-Duhem equation was ...
Parameters estimation and VLE calculation in asymmetric binary mixtures containing carbon dioxide+n-alkanols
(Elsevier Science, 2009-01)
In the present work, the estimation of the parameters for asymmetric binary mixtures of carbon dioxide + n-alkanols has been developed. The binary interaction parameter k12 of the second virial coefficient and non-random ...
Solubility of solids in supercritical fluids using equations of state — excess Gibbs free energy models
(Process Technology Proceedings, 1996)
Solubilities of several organic solids in four supercritical fluids are calculated with Soave and Peng-Robinson equations of state, incorporating excess Gibbs free energy into the mixing rules, with Heidemann-Kokal, ...
Influence of the mixing rule on the liquid-liquid equilibrium calculation
(Fluid Phase Equilibria, 1996)
Liquid-liquid equilibrium data were correlated with three mixing rules that incorporate excess Gibbs energy model into a equation of state: Wong-Sandler, Heidemann-Kokal and MHV2 methods. The Soave equation of state is ...
Influence of the mixing rule on the liquid-liquid equilibrium calculation
(1996)
Liquid-liquid equilibrium data were correlated with three mixing rules that incorporate excess Gibbs energy model into a equation of state: Wong-Sandler, Heidemann-Kokal and MHV2 methods. The Soave equation of state is ...