Artículos de revistas
Parameters estimation and VLE calculation in asymmetric binary mixtures containing carbon dioxide+n-alkanols
Fecha
2009-01Registro en:
Lopez Jimenez, Jimmy Andres; Trejos, Victor M.; Cardona, Carlos A.; Parameters estimation and VLE calculation in asymmetric binary mixtures containing carbon dioxide+n-alkanols; Elsevier Science; Fluid Phase Equilibria; 275; 1; 1-2009; 1-7
0378-3812
CONICET Digital
CONICET
Autor
Lopez Jimenez, Jimmy Andres
Trejos, Victor M.
Cardona, Carlos A.
Resumen
In the present work, the estimation of the parameters for asymmetric binary mixtures of carbon dioxide + n-alkanols has been developed. The binary interaction parameter k12 of the second virial coefficient and non-random two liquid model parameters 12 and 21 were obtained using Peng–Robinson equation of state coupled with the Wong–Sandler mixing rules. In all cases, Levenberg–Marquardt minimization algorithm was used for the parameters optimization employing an objective function based on the calculation of the distribution coefficients for each component. Vapor–liquid equilibrium for binary asymmetric mixtures (CO2 + n-alkanol, from methanol to 1-decanol) was calculated using the obtained values of the mentioned parameters. The agreement between calculated and experimental values was satisfactory.