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The mechanism of Menshutkin reaction in gas and solvent phases from the perspective of reaction electronic flux
(Springer Verlag, 2014)
© 2014, Springer-Verlag Berlin Heidelberg.The mechanism of Menshutkin reaction, NH3 + CH3Cl = [CH3–NH3]+ + Cl-, has been thoroughly studied in both gas and solvent (H2O and cyclohexane) phase. It has been found that solvents ...
NbCl5 a multifunctional reagent for the synthesis of new halogenated aminoquinoline compounds through innovative one-pot reaction and the acidochromism effect
(2018-10-18)
This paper describes an original one-pot way to synthesize nine new halogenated aminoquinoline derivatives using reactions conducted by niobium pentachloride. Subsequently, we describe an efficient and selective reduction ...
Functional nanostructured catalysts based on the niobates to the dry methane reforming and ethylene homologation reactions
(2013-01-01)
Catalytic activity and selectivity of niobate-based nanostructured materials were investigated. Dry methane reforming (DMR) and ethylene homologation reaction (EHR) were selected as test reactions. KSr 2Nb5O15, Sr2NaNb5O ...
Functional nanostructured catalysts based on the niobates to the dry methane reforming and ethylene homologation reactions
(2013-01-01)
Catalytic activity and selectivity of niobate-based nanostructured materials were investigated. Dry methane reforming (DMR) and ethylene homologation reaction (EHR) were selected as test reactions. KSr 2Nb5O15, Sr2NaNb5O ...
Prediction of effective reaction rates in catalytic systems of multiple reactions using one-dimensional models
(Elsevier Science Sa, 2018-03)
In this work two one-dimensional (1D) models are used to approximate the catalytic behavior of three-dimensional (3D) shaped pellets. One of the 1D models employs a single parameter and is identified as Generalized Cylinder ...
Quantum information from selected elementary chemical reactions: Maximum entangled transition state
(John Wiley & Sons Inc, 2015-10)
Quantum entanglement features exhibited by the reaction path of some selected elementary chemical reactions: hydrogenic abstraction, nucleophilic hydrogenic substitution, three-atom insertion reaction of silylene into ...
Total synthesis of (-)-basiliskamide B
(Wiley-blackwellMaldenEUA, 2008)
The atmospheric pressure Meerwein reaction
(John Wiley & Sons LtdChichesterInglaterra, 2006)
Competing mechanisms for the reaction of dichloropropynylborane with 2-tert-butylbutadiene. Diels-Alder reaction versus alkynylboration
(Royal Society of Chemistry, 2015-05)
Density functional theory and the quantum theory of atoms in molecules approach were used to study two competing process: the Diels-Alder reaction (DA) and the 1,4-alkynylboration (AB) between dichloropropynylborane (1) ...