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Novel Schiff base self-condensed oligomers in complexation with metallic triflates of low-band gap properties
(Springer-Verlag London Ltd, 2015)
Kinetics and photophysical behavior of the P,N-ReI complex [P,N-{(C6H5)2(C5H4N)P}Re(CO)3(O-O3SCF3)]: A directly coordinated (and labile) triflate
(Elsevier Ltd, 2017)
© 2017 Elsevier Ltd The reaction of [P,N-{(C6H5)2(C5H4N)P}Re(CO)3Br] (RePNBr) with silver triflate leads to the complex [P,N-{(C6H5)2(C5H4N)P}Re(CO)3(O-CF3SO3)] (RePNTfO) with moderate yield. This new P,N-ReI triflate ...
Kinetics and photophysical behavior of the P,N-Re-I complex [P,N-{(C6H5)(2)(C5H4N)P}Re(CO)(3)(O-O3SCF3)]: a directly coordinated (and labile) triflate
(Elsevier, 2017)
The reaction of [P,N-{(C6H5)(2)(C5H4N)P}Re(CO)(3)Br] (RePNBr) with silver triflate leads to the complex [P,N-{(C6H5)(2)(C5H4N)P}Re(CO)(3)(O-CF3SO3)] (RePNTfO) with moderate yield. This new P,N-Re-I triflate compound contains ...
Catalytic, regioselective, and green methods for rearrangement of 1,2-diaryl epoxides to carbonyl compounds employing metallic triflates, Brønsted-acidic ionic liquids (ILs), and IL/microwave; experimental and computational substituent effect study on aryl versus hydrogen migration
(Elsevier Science, 2014-08)
The Lewis-acid catalyzed rearrangement of parent trans-stilbene oxide 1 was studied with M(OTf)3/DCM and M(OTf)3/[BMIM][BF4] (M = Bi, Al, Ga, Sc, and Yb; [BMIM] = butylmethylimidazolium) and Zn(NTf2)2, and with Bi(OTf)3/[BMIM][X] ...
Electrophilic addition of Propargylic cations to allenes: formation of crowded Chloro- and Azido-Enynes by trapping of the resulting allylic cations with TMSX (X = Cl, N3): a synthetic and computational study
(Wiley VCH Verlag, 2013-07)
Propargylic cations, generated by the ionization of propargyl alcohols with catalytic amounts of Bi(OTf)3, react with arylsubstituted allenes to generate incipient allylic cations that are quenched in the presence of TMSCl ...
Síntese e caracterização de fases de líquidos iônicos imobilizadas em polímero contendo triflato de escâncio
(Universidade Federal de São Paulo, 2022-04-29)
O uso de líquidos iônicos em reações orgânicas é bem explorado na literatura, porém o seu alto custo e sua elevada viscosidade representam dificuldades para sua aplicação em escala industrial. Estas limitações podem ser ...
Recent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating Reagents
(Wiley, 2014-10)
Electrophilic trifluoromethylation reactions have been the latest approach to achieve the fluoroalkylation of compounds with newly-discovered reagents, such as the Togni’s (1-trifluoromethyl-1,2-benziodoxol-3-(1 H)-one), ...