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Nucleofugality index in alpha-elimination reactions
(2007)
We propose that a specific property of a chemical fragment, its regional electrophilicity, be taken as defining its nucleofugality index nu(PG) in alpha-elimination reactions. We tabulate this quantity for a series of ...
Homofugality: a new reactivity index describing the leaving group ability in homolytic substitution reactions
(ELSEVIER SCIENCE PUBLISHERS B.V., 2006)
Towards an intrinsic nucleofugality scale: the leaving group (lg) ability in ch(3)lg model system
(ELSEVIER SCIENCE PUBLISHERS B.V., 2006)
beta-Scission of thioimidoyl radicals (R-1-N-C-center dot=S-R-2): A theoretical scale of radical leaving group ability
(2007)
A theoretical study of the beta-scission reactions for some thioimidoyl radicals (R-1-N=C-center dot-S-R-2) using a recently introduced homofugality index, nu(center dot) is presented. This index, that was defined as a ...
Towards an intrinsic nucleofugality scale: The leaving group (LG) ability in CH(3)LG model system
(ELSEVIER, 2006-03-10)
For an important class of organic reactions in which a fragment of the reactants, the leaving group (LG) or nucleofuge (Z), is detached of the substrate bearing the bonding electron pair, the global electrophilicity index ...
Homofugality: A new reactivity index describing the leaving group ability in homolytic substitution reactions
(ELSEVIER, 2006-06-24)
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank the leaving group ability of radical fragments present in homolytic substitution reactions. The model is validated for a ...
Homofugality: a new reactivity index describing the leaving group ability in homolytic substitution reactionsCHEMICAL PHYSICS LETTERSCHEM PHYS LETT
(ELSEVIER SCIENCE PUBLISHERS B.V., 2017)
Towards an intrinsic nucleofugality scale: the leaving group (lg) ability in ch(3)lg model systemCHEMICAL PHYSICS LETTERSCHEM PHYS LETT
(ELSEVIER SCIENCE PUBLISHERS B.V., 2017)
Work Ability and Musculoskeletal Disorders Among Workers From a Public Health Institution
(Central Inst Labour Protection-natl Research InstWarsawPolónia, 2009)
KINETICS AND MECHANISM OF THE AMINOLYSIS OF 2,4-DINITROPHENYL AND 2,4,6-TRINITROPHENYL THIOLACETATES
(ROYAL SOC CHEMISTRY, 1991)
The reactions of the title substrates with alicyclic secondary amines and pyridines are subject to a kinetic study in water [25-degrees-C, ionic strength 0.2 mol dm-3 (KCl)]. The Bronsted-type plots obtained for all ...