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Iso-solvation effects in mixtures of ionic liquids on the kinetics of a model SNAr reaction
(2017)
The SNAr reaction between 1-chloro-2,4-dinitrobenzene and morpholine was used as a model system to study solvation effects in a series of mixtures involving imidazolium based ionic liquids. Iso-solvation regimes (i.e. a ...
Solvent effect on a model SNAr reaction in ionic liquid/water mixtures at different compositions
(2018)
The reaction of phenyl 2,4,6-trinitrophenyl ether and piperidine was kinetically evaluated in BMIMBF4/ water mixtures as the reaction media. This study shows the dramatic effect of the mixture composition on the reacting ...
Iso-solvation effects in mixtures of ionic liquids on the kinetics of a model snar reaction
(2017)
The SNAr reaction between 1-chloro-2,4-dinitrobenzene and morpholine was used as a model system to study solvation effects in a series of mixtures involving imidazolium based ionic liquids. Iso-solvation regimes (i.e. a ...
Iso-solvation effects in mixtures of ionic liquids on the kinetics of a model SNAr reaction
(Royal Society Chemistry, 2017)
The SNAr reaction between 1-chloro-2,4-dinitrobenzene and morpholine was used as a model system to study solvation effects in a series of mixtures involving imidazolium based ionic liquids. Iso-solvation regimes (i.e. a ...
Estimating reaction constants by ab initio molecular modeling: a study on the oxidation of phenol to catechol and hydroquinone in advanced oxidation processes
(Brazilian Society of Chemical Engineering, 2012)
Molecular modeling is growing as a research tool in Chemical Engineering studies, as can be seen by a simple research on the latest publications in the field. Molecular investigations retrieve information on properties ...
Molecular dynamics studies of amylose plasticized with Brazilian Cerrado oils : part I
(Associação Brasileira de Polímeros, 2018)
Biodegradable polymers have become part of the realm of polymer science with specially when associated to renewable sources. Unraveling the plasticizer effect of natural occurring fatty acids in the Brazilian Cerrado on ...
Phospha- and arsa-bridged cyclononatetraenides: Novel zwitterionic 10π aromatic hemispheres
(Royal Society of Chemistry, 2019-03)
The structural/geometrical features, multinuclear GIAO-NMR characteristics, tropicity, nucleus independent chemical shift NICS(1) and NICS(1)zz values, and NPA charge densities for phosphatriquinacene, its P-methylated ...
Biobased plasticizer from agroindustrial residual streams
(Universidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería QuímicaFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá, 2023-05-17)
Biobased plasticizer from agro-industrial residual streams
Soybean Oil Deodorizer Distillate (SODD) is a valuable agro-industrial waste stream that can be used as feedstock for a wide range of oleochemicals. In this regard, ...