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Kinetics and Mechanism of Gas-Phase Thermolysis Using Headspace-Gas Chromatographic Analysis
(Oxford University Press, 2001-02)
Headspace gas chromatography is employed in order to study the thermal decomposition reaction of gaseous di-tert-butyl peroxide (DTBP) in the 130°C to 160°C temperature range and in the presence of n-hexane as the internal ...
Theoretical study of the gas-phase thermolysis of 3-methyl-1,2,4,5- tetroxane
(Springer Verlag, 2014)
Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography
(Gupta Publications, 2020-02)
Gas phase thermolysis reaction of glutaraldehyde acid diperoxide (3,6-dibutanoic -1,2,4,5-tetroxane,DPAG) was performed in an injection chamber of a gas chromatograph as a constant time thermal flow reactor, has been applied ...
Theoretical study of the gas-phase thermolysis reaction of 3,6-dimethyl-1,2,4,5-tetroxane. Methyl and axial-equatorial substitution effects
(Springer, 2019-07)
Organic peroxides are interesting compounds with a broad range of properties from antimalarial and antimicrobial activities to explosive character. In this work the gas-phase thermolysis reaction mechanism of the ...
Co-thermolysis: A one-pot synthetic method for novel 2-substituted-5- (trifluoromethoxy)thiophenes
(Pergamon-Elsevier Science Ltd, 2010-10)
A new 'green' process to obtain trifluoromethoxylated compounds by a gas-phase method has been accomplished. Through it, new 2-substituted-5- (trifluoromethoxy)thiophenes have been obtained in moderate to good yields. ...
Theoretical study of the thermolysis reaction of Ethyl β-hydroxycarboxylates in the gas phase
(2002)
Theoretical studies on the thermolysis of three ethyl β-hydroxycarboxylates in the gas phase were carried out using ab initio theoretical methods, at the MP2/6-31G(d) and MP2/6-311++G(2d,p)//MP2/6-31G(d) levels of theory. ...
Rearomatization of trifluoromethyl sulfonyl dihydropyridines: Thermolysis vs photolysis
(John Wiley & Sons Ltd, 2017-12)
In this article, we describe the static gas-phase pyrolysis, microwave-induced pyrolysis, and photolysis reactions of trifluoromethyl sulfonyl dihydropyridines. The goal of this work was to find a methodology that allows ...
Theoretical study of the gas-phase decomposition of neutral α-amino acid ethyl esters. Part 1 - The elimination of N,N-dimethylglycine ethyl ester and ethyl 1-piperidineacetate
(2002)
Theoretical studies of the thermolysis of two α-amino acid ethyl esters in the gas phase were carried out using ab initio theoretical methods, at the HF/6-31G(d) and the MP2/6-311 + G(2d,p)//MP2/6-31G(d) levels of theory. ...
Study of the interaction between oligomers from the heavy fraction of the bio-oil and the catalyst in hydrotreatment process
(Universidad Nacional de ColombiaMedellín - Minas - Doctorado en Ingeniería - Sistemas EnergéticosFacultad de MinasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín, 2023-06-05)
Biomass fast pyrolysis bio-oil is a promising alternative to be used as a source of fuels and chemicals. It hosts a wide variety of compounds and comes from renewable sources. Pyrolysis oil is formed by water, light organics ...