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Operation of FCC with mixtures of regenerated and deactivated catalyst
(Elsevier Science, 2001-07)
The operation of FCC with mixtures of coked and regenerated catalyst was studied with a riser simulator reactor on two equilibrium catalysts at 550◦C. The coked catalysts maintain an activity level that enables them to be ...
Phenol methylation on acid catalysts: Study of the catalyst deactivation kinetics and mechanism
(Elsevier Science, 2014-01)
The kinetics and mechanism of coke formation and catalyst deactivation during the synthesis of cresols from phenol methylation were investigated on SiO2–Al2O3, tungstophosphoric acid (HPA) supported on silica, and zeolites ...
Simultaneous deactivation by coke and sulfur of Pt-Re(Ge,Sn)/Al2O3 catalysts for n-hexane reforming
(Elsevier Science, 2000-04)
The simultaneous deactivation by coke and sulfur of monometallic Pt/Al2O3 and bimetallic Pt–Re(Ge, Sn)/Al2O3 catalysts was studied using n-hexane reforming as bifunctional test reaction and thiophene as poisoning molecule. ...
Progress of the Catalytic Deactivation of H-ZSM-5 Zeolite in Glycerol Dehydration
(2021-01-01)
Glycerol conversion into value-added chemicals has received much attention due to the prospect of increasing the biodiesel industry‘s profitability. The dehydration of glycerol is one of the most explored reactions in the ...
Isobutane/Butene Alkylation:regeneration of solid acid catalysts
(Elsevier Science, 2000-11)
The regeneration of Y-zeolite catalysts used during the isobutane alkylation reaction is studied. Coke is characterized by temperature-programmed techniques and measuring the H/C ratio. The coke deposited under supercritical ...
Acylation of phenol on solid acids: Study of the deactivation mechanism
(Elsevier Science, 2005-10)
The deactivation mechanism of the gas-phase synthesis of o-hydroxyacetophenone (o-HAP) via acylation of phenol with acetic acid was studied on Al-MCM-41 and zeolites HY, HBeta and HZSM-5. The o-HAP yield remained constant ...
Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties
(Elsevier, 2018-08)
The impact of the composition of the various hydrocarbon fractions in a conventional VGO (saturated SF, aromatic AF and resin RF) and the whole VGO on the coke formed in their catalytic cracking was evaluated over two Y ...
Effects of crystal size, acidity, and synthesis procedure on the catalytic performance of gallium and aluminum MFI zeolites in glycerol dehydration
(2016-10-01)
The influence on gas-phase catalytic glycerol dehydration of crystal size (S: small, or L: large crystals), acidity, and synthesis procedure for isomorphous incorporation of gallium (Ga-S; Ga-L) or aluminum (Al-S; Al-L) ...
Deactivation of ferrierite during the skeletal isomerization of linear butenes
(Springer, 2001-01)
Deactivation of ferrierite during the skeletal isomerization of 1-butene at atmospheric pressure and 0.15 atm 1-butene partial pressure was studied. At 300°C, the carbon content shows a sharp increase during the first 30 ...