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A simple protocol for the physical cleavage of Trypanosoma cruzi kinetoplast DNA present in blood samples and its use in polymerase chain reaction (PCR)-based diagnosis of chronic Chagas disease
(Fundação Oswaldo Cruz. Instituto Oswaldo Cruz., 2020)
S-H bond cleavage in molecules of biological interest with CpFe(dppe)I
(2000)
The reaction of CpFe(dppe)I (Cp, cyclopentadienyl; dppe, Ph2P(CH2)(2)PPh2) with biologically active RSH molecules (L-cysteine hydrochloride, dithiothereitol and 2-mercaptoethanol) in the presence of NH4PF6 and in methanol ...
The aromatic carbon-carbon ipso-substitution reaction
(Wiley VCH Verlag, 2010-12)
The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based ...
Molecular chaperone Hsp90 as a target for oxidant-based anticancer therapies
(2011)
Hsp90 is a molecular chaperone involved in the stabilization of many oncoproteins that are required for the acquisition and maintenance of the so-called six major hallmarks of cancer cells. Various strategies have, therefore, ...
A simple protocol for the physical cleavage of Trypanosoma cruzi kinetoplast DNA present in blood samples and its use in polymerase chain reaction (PCR)-based diagnosis of chronic Chagas disease
(Fundação Oswaldo Cruz. Instituto Oswaldo Cruz., 1993)
End-group differentiating ozonolysis of norbornene systems to access to highly substituted cyclopentane rings
(Wiley, 2013-05)
The end-group-differentiating ozonolysis concept is discussed, with an emphasis on norbornene systems. Different remote functional groups in endo positions in norbornene derivatives are able to direct the primary ozonide ...
Atomic Sulfur Formation Mechanism on 3-mercaptopropanoic Acid-Derivatives SAMs: Understanding the C-S Bond Cleavage
(American Chemical Society, 2019-09)
Self-assembled monolayers (SAMs) of ω-carboxylic acid thiols are very important in the surface modification of metals, especially on gold surfaces. Indeed, the 3-mercaptopropanoic acid (MPA) and its ester or amide derivatives ...
Prediction of catalytic activity of Pt3Re1 alloy for C-C bond cleavage in the ethanol oxidation reaction
(2016-05-30)
Design of catalysts able to cleave C-C bond in ethanol oxidation reaction at low temperatures is primordial for improving the direct ethanol proton exchange membrane fuel cells. Pt-Re alloy seems to be an appropriate ...