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Cu(II)–Gd(III) 2D-coordination polymer based on two different organic linkers
(Elsevier, 2017)
A new CuII–GdIII heterometallic coordination polymer was obtained by a two-step synthesis, using the
molecular complex [Cu(H2IDC)2(2,20-bipy)] 2H2O (1) as metalloligand and oxalate as auxiliary ligand
(H3IDC = ...
Shape-persistent fluorescent tetraphenylmethane dendrimers
(ROYAL SOC CHEMISTRY, 2016)
We report the first examples of a new class of rigid dendrimers made of three-dimensional tetraphenylmethane units connected by ethynylene linkers. Designed to obtain a persistent globular shape, minimal backfolding of ...
Pyrazolyl coordination polymers of cadmium(II)
(Elsevier B.V., 2006-02-01)
The coordination polymers [Cd(mu-Cl)(2)(HPz)(2)](n) (1) and [Cd(mu-1,3-SCN)(2)(HPz)(2)](n) (2) (HPz = pyrazole) have been prepared and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray ...
Pyrazolyl coordination polymers of cadmium(II)
(Elsevier B.V., 2006-02-01)
The coordination polymers [Cd(mu-Cl)(2)(HPz)(2)](n) (1) and [Cd(mu-1,3-SCN)(2)(HPz)(2)](n) (2) (HPz = pyrazole) have been prepared and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray ...
Molecular Networks in Dynamic Multilevel Systems
(Wiley VCH Verlag, 2018-09)
Dynamic multilevel systems can be assembled from molecular building blocks through two or more reversible reactions that form covalent bonds. Molecular networks of dynamic multilevel systems can exhibit different connectivities ...
Signaling properties of a covalent modification cycle are altered by a downstream target
(National Academy of Sciences, 2010-06)
We used a model system of purified components to explore the effects of a downstream target on the signaling properties of a covalent modification cycle, an example of retroactivity. In the experimental system used, a ...
Engineering multilayer chemical networks
(Royal Society of Chemistry, 2019-09)
Dynamic multilevel systems emerged in the last few years as new platforms to study thermodynamic systems. In this work, unprecedented fully communicated three-level systems are studied. First, different conditions were ...
Synthesis of silver nanoparticles coated with OH-functionalized organic groups: Dispersion and covalent bonding in epoxy networks
(American Chemical Society, 2010-02)
The introduction of reactive functionalities in the organic groups used, to stabilize inorganic nanoparticles (NPs) enables multiple applications based on their covalent fixation to a variety of materials, substrates and ...
Vinylogous urethane vitrimers
(Wiley VCH Verlag, 2015-03-13)
Vitrimers are a new class of polymeric materials with very attractive properties, since they can be reworked to any shape while being at the same time permanently cross-linked. As an alternative to the use of transesterification ...
Influence of β-Cyclodextrin Methylation on Host-Guest Complex Stability: A Theoretical Study of Intra- and Intermolecular Interactions as Well as Host Dimer Formation
(2023)
Understanding the non-covalent interactions in host-guest complexes is crucial to their stability, design and applications. Here, we use density functional theory to compare the ability of β-cyclodextrin (β-CD) and ...