artículo
Shape-persistent fluorescent tetraphenylmethane dendrimers
Fecha
2016Registro en:
10.1039/c6py01046f
1759-9962
1759-9954
WOS:000384237200006
Autor
Urzua, Julio I.
Regueira, Maria A.
Lazzari, Massimo
Torneiro, Mercedes
Institución
Resumen
We report the first examples of a new class of rigid dendrimers made of three-dimensional tetraphenylmethane units connected by ethynylene linkers. Designed to obtain a persistent globular shape, minimal backfolding of terminal groups and well-defined cavities at low generations, the dendrimers were synthesized until the second generation by a convergent strategy based on Sonogashira couplings. Their structure and size were confirmed by NMR, MALDI-TOF-MS and SEC among other techniques. The dendrimers showed intrinsic fluorescence with quantum yields of similar to 0.6.