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Substituent effects on the photolysis of methyl 2-carboxylate substituted aliphatic 2H-azirines
(Elsevier Science, 2007-05)
In this study, the UV induced photochemical reactions of two 2H-azirines – methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) and methyl 3-methyl-2H-azirine-2-carboxylate (MMAC) – isolated in argon matrices are ...
PREPARATION OF SOME TRANS-BIS(2H-AZIRINE)PALLADIUM DICHLORIDE COMPLEXES AND THE OPENING OF THEIR AZIRINE RINGS IN BENZENE
(Elsevier Science Sa LausanneLausanne 1Suíça, 1984)
Unusual Photochemical C-N Bond Cleavage in the Novel Methyl 2-Chloro-3-methyl-2H-azirine-2-carboxylate
(American Chemical Society, 2006-07)
The structure, preferred conformers, vibrational spectrum, and photochemical behavior of the novel azirine, methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) were investigated in low-temperature matrixes and in the ...
Methyl 3-methyl-2H-azirine-2-carboxylate photochemistry studied by matrix-isolation FTIR and DFT calculations
(American Chemical Society, 2006-08)
The aliphatic 2H-azirine, methyl 3-methyl-2H-azirine-2-carboxylate (MMAC), has been synthesized and its monomeric form investigated by IR spectroscopy in an argon matrix, at 10 K, as well as theoretically (DFT/B3LYP/6-31 ...
Site selectivity in the reaction of 2-formyl-2H-azirine-N-arylimines with diphenylketene
(Hetero CorporationOdessa, 1997)
Electronically mediated selectivity in ring opening of 1-azirines. The 3-z mode: Convenient route to 2-aza-1,3-dienes
(Amer Chemical SocWashingtonEUA, 1999)
Structure and photochemical behaviour of 3-azido-acrylophenones: a matrix isolation infrared spectroscopy study
(Pergamon-Elsevier Science Ltd, 2011-10)
(Z)-3-Azido-3-methoxycarbonyl-2-chloro-acrylophenone (MACBP) has been synthesized, isolated in low temperature argon and xenon matrices and studied by FTIR spectroscopy, complemented by DFT(B3LYP)/6-311++G(d,p) calculations. ...