Asymmetric and Symmetric Triazenido Cyclopalladated Complexes: Synthesis, Structural Analysis and DFT Calculations

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorVaniel, Ana Paula HÄrter
dc.creatorMauro, Antonio Eduardo
dc.creatorNetto, Adelino Vieira de Godoy
dc.creatorAlmeida, Eduardo Tonon de
dc.creatorPiquini, Paulo Cesar
dc.creatorZambiazi, Priscilla
dc.creatorBack, Davi Fernando
dc.creatorHörner, Manfredo
dc.date2015-05-15T13:30:25Z
dc.date2016-10-25T20:48:43Z
dc.date2015-05-15T13:30:25Z
dc.date2016-10-25T20:48:43Z
dc.date2014
dc.date.accessioned2017-04-06T08:17:16Z
dc.date.available2017-04-06T08:17:16Z
dc.identifierJournal of Molecular Structure, v. 1083, p. 311-318, 2014.
dc.identifier0022-2860
dc.identifierhttp://hdl.handle.net/11449/123565
dc.identifierhttp://acervodigital.unesp.br/handle/11449/123565
dc.identifierhttp://dx.doi.org/10.1016/j.molstruc.2014.11.069
dc.identifier7927677053650819
dc.identifier6402668883583711
dc.identifier8922528250830998
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/934176
dc.descriptionThe reaction of [Pd{dmba}(l-N3)]2 (dmba = N,N-dimethylbenzylamine) with 1-(2-fluorophenyl)-3-(4- nitrophenyl)triazenido (L1 ) or 1,3-bis(4-nitrophenyl)triazenido (L2 ) anions, in methanol, and subsequent treatment with pyridine (py) allows the preparation of the corresponding cyclopalladated compounds [Pd(dmba)(L1 )(py)] (1) and [Pd(dmba)(L2 )(py)]py (2). The acentric mononuclear entities of (1) and (2) are connected by weak intermolecular non-classical CAHC hydrogen bonds, which results in 2-D arrangements by translation, along the [1 0 0] and [0 01] crystallographic directions, respectively.
dc.languageeng
dc.relationJournal of Molecular Structure
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjecttriazenido ligand
dc.subjectsupramolecular arrangement
dc.subjectcyclopalladated complex
dc.subjectNon-classical CH C hydrogen bond
dc.titleAsymmetric and Symmetric Triazenido Cyclopalladated Complexes: Synthesis, Structural Analysis and DFT Calculations
dc.typeOtro


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