Development of a biosponge based on Luffa cylindrica and crosslinked chitosan for Allura red AC adsorption

dc.creatorSchio, Rejiane R.
dc.creatorGonçalves, Janaína
dc.creatorMallmann, Evandro S.
dc.creatorPinto, Diana
dc.creatorDotto, Guilherme Luiz
dc.date2021-11-17T16:28:19Z
dc.date2021-11-17T16:28:19Z
dc.date2021
dc.date2022
dc.date.accessioned2023-10-03T20:02:58Z
dc.date.available2023-10-03T20:02:58Z
dc.identifier0141-8130
dc.identifier1879-0003
dc.identifierhttps://hdl.handle.net/11323/8871
dc.identifierhttps://doi.org/10.1016/j.ijbiomac.2021.10.096
dc.identifierCorporación Universidad de la Costa
dc.identifierREDICUC - Repositorio CUC
dc.identifierhttps://repositorio.cuc.edu.co/
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9174105
dc.descriptionA new bioadsorbent from Luffa cylindrica and cross-linked chitosan was proposed in the present study. Luffa was used as a natural support medium for chitosan crosslinked with glutaraldehyde (LCsG) and epichlorohydrin (LCsE). Biosponges were applied to remove Allura red from aqueous solutions. LCsG and LCsE were produced using different concentrations of chitosan (1%, 3% and 5% (m v−1)) and crosslinking agents (0.5%, 1.0% and 1.5% (v v−1)). Based on the FT-IR spectra, functional groups characteristic of chitosan crosslinked with glutaraldehyde and epichlorohydrin confirmed the crosslinking. In addition, the biosorbent revealed highly efficient functional groups and morphology with irregularities favorable for adsorption. It was found that the increase in the percentage of glutaraldehyde and epichlorohydrin increased the sample's swelling degree, and the degree of cross-linking was greater than 80% for all LCsG. The results regarding the degree of swelling and degree of crosslinking corroborated with the evaluation of the biosponge's adsorptive potential. The Sips model predicted the equilibrium isotherms, with a maximum adsorption capacity of 89.05 mg g−1 for LCsG and 60.91 mg g−1 for LCsE. The new procedure was successful. Luffa was excellent support for chitosan, resulting in an attractive, low-cost bioadsorbent, preventing renewable sources.
dc.formatapplication/pdf
dc.formatapplication/pdf
dc.languageeng
dc.publisherCorporación Universidad de la Costa
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dc.rightsCC0 1.0 Universal
dc.rightshttp://creativecommons.org/publicdomain/zero/1.0/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightshttp://purl.org/coar/access_right/c_abf2
dc.sourceInternational Journal of Biological Macromolecules
dc.sourcehttps://www.sciencedirect.com/science/article/pii/S0141813021022534#!
dc.subjectLuffa cylindrica
dc.subjectCrosslinked
dc.subjectChitosan
dc.subjectAdsorption
dc.titleDevelopment of a biosponge based on Luffa cylindrica and crosslinked chitosan for Allura red AC adsorption
dc.typePre-Publicación
dc.typehttp://purl.org/coar/resource_type/c_816b
dc.typeText
dc.typeinfo:eu-repo/semantics/preprint
dc.typeinfo:eu-repo/semantics/draft
dc.typehttp://purl.org/redcol/resource_type/ARTOTR
dc.typeinfo:eu-repo/semantics/acceptedVersion
dc.typehttp://purl.org/coar/version/c_ab4af688f83e57aa


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