Degradation of diclofenac aqueous solutions in a 3D electrolytic reactor using carbon-based materials as pseudo third electrodes in fluidized bed, anodic and cathodic configurations

dc.creatorAcuna-Bedoya, Jawer David
dc.creatorAlvarez Pugliese, Christian Eduardo
dc.creatorCastilla-Acevedo, Samir
dc.creatorBravo Suarez, Juan
dc.creatorMarriaga-Cabrales, Nilson
dc.date2022-07-21T19:59:21Z
dc.date2022-07-21T19:59:21Z
dc.date2022
dc.date.accessioned2023-10-03T20:01:29Z
dc.date.available2023-10-03T20:01:29Z
dc.identifierJawer David Acuña-Bedoya, Christian E. Alvarez-Pugliese, Samir Fernando Castilla-Acevedo, Juan J. Bravo-Suárez, Nilson Marriaga-Cabrales, Degradation of diclofenac aqueous solutions in a 3D electrolytic reactor using carbon-based materials as pseudo third electrodes in fluidized bed, anodic and cathodic configurations, Journal of Environmental Chemical Engineering, Volume 10, Issue 4, 2022, 108075, ISSN 2213-3437, https://doi.org/10.1016/j.jece.2022.108075. (https://www.sciencedirect.com/science/article/pii/S2213343722009484)
dc.identifier2213-3437
dc.identifierhttps://hdl.handle.net/11323/9392
dc.identifierhttps://doi.org/10.1016/j.jece.2022.108075
dc.identifierCorporación Universidad de la Costa
dc.identifierREDICUC - Repositorio CUC
dc.identifierhttps://repositorio.cuc.edu.co/
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9173941
dc.descriptionIn this study, the degradation of diclofenac (DCF) in a 3D electrochemical reactor was evaluated. Several parameters were studied including the reactor configuration: fluidized bed (FB), anodic packed bed (APB) and cathodic packed bed (CPB); and the type of pseudo third electrode material: granular activated carbon (GAC) and granular expanded graphite (GEG). The configuration that showed the highest total organic carbon (TOC) removal was the APB, with values up to 85%. In addition, when the substrate saturation of the pseudo third electrode was 20% in the APB, the energy consumption was 2.5 times lower than the conventional 2D reactor. This efficient conversion was the result of improved contacting and reaction between hydroxyl (HO•) and sulfate (SO4•-) radicals electro-generated on the anode surface and DCF adsorbed on the particulate carbon. While the degradation efficiency with the 3D CPB reactor was higher than the FB configuration, it was less effective than the 3D APB reactor because of H2O2 production in the cathode, which decomposed to generate HO•, but only slowly and not sufficiently to oxidize DCF to a significant extent. Furthermore, it was also found that when two 3D APB reactors were connected in series a more significant TOC decrease (98%) and lower energy consumption (4 times) could be achieved than in a single 2D reactor configuration. This result demonstrated that the 3D electrochemical process can be cheaper and faster. All these results highlight the 3D anodic electro-oxidation process as a potential technology to efficiently treat recalcitrant contaminants of emerging concern.
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dc.languageeng
dc.publisherElsevier Ltd.
dc.publisherColombia
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dc.rightsAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)
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dc.sourcehttps://www.sciencedirect.com/science/article/pii/S2213343722009484
dc.subject540 - Química y ciencias afines::546 - Química inorgánica
dc.subjectBoron doped diamond
dc.subjectElectro-oxidation
dc.subjectAdsorption
dc.subjectGranular activated carbon
dc.subjectGranular expanded graphite
dc.titleDegradation of diclofenac aqueous solutions in a 3D electrolytic reactor using carbon-based materials as pseudo third electrodes in fluidized bed, anodic and cathodic configurations
dc.typeArtículo de revista
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