Comparative adsorption of tetracycline onto unmodified and NaOH-modified silicomanganese fumes: kinetic and process modeling

dc.creatorSaood Manzar, Mohammad
dc.creatorAhmad, Tauqir
dc.creatorZubair, Mukarram
dc.creatorUllah, Nisar
dc.creatorAlqahtani, Hissah A.
dc.creatorda Gama, V. Brigida Maria
dc.creatorGeorgin, Jordana
dc.creatorNasir, Muhammad
dc.creatorDalhat Mu'azu, Nuhu
dc.creatorAl Ghamdi, Jwaher M.
dc.creatorAbdul Aziz, Hamidi
dc.creatorMeili, Lucas
dc.date2023-09-06T14:10:29Z
dc.date2025
dc.date2023-09-06T14:10:29Z
dc.date2023
dc.date.accessioned2023-10-03T19:11:33Z
dc.date.available2023-10-03T19:11:33Z
dc.identifierMohammad Saood Manzar, Tauqir Ahmad, Mukarram Zubair, Nisar Ullah, Hissah A. Alqahtani, Brigida Maria V. da Gama, Jordana Georgin, Muhammad Nasir, Nuhu Dalhat Mu'azu, Jwaher M. Al Ghamdi, Hamidi Abdul Aziz, Lucas Meili, Comparative adsorption of tetracycline onto unmodified and NaOH-modified silicomanganese fumes: Kinetic and process modeling, Chemical Engineering Research and Design, Volume 192, 2023, Pages 521-533, ISSN 0263-8762, https://doi.org/10.1016/j.cherd.2023.02.047.
dc.identifier0263-8762
dc.identifierhttps://hdl.handle.net/11323/10450
dc.identifier10.1016/j.cherd.2023.02.047
dc.identifier1744-3563
dc.identifierCorporación Universidad de la Costa
dc.identifierREDICUC - Repositorio CUC
dc.identifierhttps://repositorio.cuc.edu.co/
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9168714
dc.descriptionSilicomanganese fumes (SMF) are industrial waste and a potential low-cost adsorbent for the removal of contaminants from water. In this study, the adsorption performance of SMF and NaOH-modified SMF (SMF-Na) for the removal of tetracycline (TC) from an aqueous solution was investigated. The characterization results showed the presence of functional groups (SiO2, -OH and C-O-C), a considerably higher surface area of the SMF-Na (142.59 m2 g−1) compared to the SMF (7.73 m2 g−1). The TC adsorption was favored under acidic conditions (pH 2–3) and increased with an increasing amount of adsorbent. The adsorption equilibrium was achieved in 360 min, and the presence of Na+ ions insignificantly influenced the TC adsorption. The Avrami model fitted better to the kinetic data with R2 = 0.995. The isothermal data was well represented by the Redlich-Peterson and Langmuir model. The maximum monolayer adsorption capacity of SMF and SMF-Na was 117 and 129 mg g−1, respectively. The thermodynamic results confirmed that the TC adsorption was endothermic and predominantly governed by physical forces. The removal of TC onto SMF and SMF-Na was maintained above 90 % even after five regeneration cycles The results suggested that SMF-Na is a promising alternative adsorbent for the removal of tetracycline antibiotics from wastewater streams.
dc.format1 página
dc.formatapplication/pdf
dc.formatapplication/pdf
dc.languageeng
dc.publisherInstitution of Chemical Engineers
dc.publisherUnited Kingdom
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dc.rights© 2023 Institution of Chemical Engineers. Published by Elsevier Ltd. All rights reserved.
dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.rightshttp://purl.org/coar/access_right/c_f1cf
dc.sourcehttps://www.sciencedirect.com/science/article/abs/pii/S0263876223001430
dc.subjectTetracycline
dc.subjectSilicomanganeso
dc.subjectNaOH
dc.titleComparative adsorption of tetracycline onto unmodified and NaOH-modified silicomanganese fumes: kinetic and process modeling
dc.typeArtículo de revista
dc.typehttp://purl.org/coar/resource_type/c_2df8fbb1
dc.typeText
dc.typeinfo:eu-repo/semantics/article
dc.typehttp://purl.org/redcol/resource_type/ART
dc.typeinfo:eu-repo/semantics/draft
dc.typehttp://purl.org/coar/version/c_b1a7d7d4d402bcce


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