Simple One-Pot Synthesis of New Derivatives of the Macrocyclic Aminal 1,3,7,9,13,15,19,21-octaazapentacyclo-[19.3.1.13,7.19,13.115,19]octacosane (OAPO)

dc.creatorAlcázar Franco, Daniel Jesús
dc.date2018-11-22T15:02:50Z
dc.date2018-11-22T15:02:50Z
dc.date2013
dc.date.accessioned2023-10-03T18:59:12Z
dc.date.available2023-10-03T18:59:12Z
dc.identifier1532-2432
dc.identifierhttp://hdl.handle.net/11323/1710
dc.identifierCorporación Universidad de la Costa
dc.identifierREDICUC - Repositorio CUC
dc.identifierhttps://repositorio.cuc.edu.co/
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9166681
dc.descriptionA series of 2,2′-(dihydropyrimidine-1,3(2H,4H)-diyldimethanediyl)bis(substituted-phenols) was synthesized using a Mannich-type reaction between the macrocyclic aminal 1,3,7,9,13,15,19,21- ctaazapentacyclo[19.3.1.13,7.19,13.115,19]octacosane (OAPO) (1) and substituted phenols in basic media. These previously unreported compounds were separated from the reaction mixture by column chromatography in highly pure form with 25–75% yields. The most stable conformer was predicted using AM1-type semiempirical quantum chemical calculations
dc.formatapplication/pdf
dc.languageeng
dc.publisherUniversidad de la Costa CUC
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightshttp://purl.org/coar/access_right/c_abf2
dc.subjectAnomeric effect
dc.subjectHexahydropyrimidine
dc.subjectMannich bases
dc.subjectOrtho-regioselectivity
dc.titleSimple One-Pot Synthesis of New Derivatives of the Macrocyclic Aminal 1,3,7,9,13,15,19,21-octaazapentacyclo-[19.3.1.13,7.19,13.115,19]octacosane (OAPO)
dc.typeArtículo de revista
dc.typehttp://purl.org/coar/resource_type/c_6501
dc.typeText
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typehttp://purl.org/redcol/resource_type/ART
dc.typeinfo:eu-repo/semantics/acceptedVersion
dc.typehttp://purl.org/coar/version/c_ab4af688f83e57aa


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