Brasil
| Artigo
The reverse fluorine Perlin-like effect and related stereoelectronic interactions
| dc.creator | Silla, Josué M. | |
| dc.creator | Freitas, Matheus P. | |
| dc.creator | Cormanich, Rodrigo A. | |
| dc.creator | Rittner, Roberto | |
| dc.date | 2020-07-12T23:41:26Z | |
| dc.date | 2020-07-12T23:41:26Z | |
| dc.date | 2014-06-06 | |
| dc.date.accessioned | 2023-09-28T20:09:12Z | |
| dc.date.available | 2023-09-28T20:09:12Z | |
| dc.identifier | SILLA, J. M. et al. The reverse fluorine Perlin-like effect and related stereoelectronic interactions. Journal of Organic Chemistry, [S.l.], v. 79, n. 13, p. 6385-6388, June 2014. DOI: 10.1021/jo501025a. | |
| dc.identifier | https://pubs.acs.org/doi/10.1021/jo501025a | |
| dc.identifier | http://repositorio.ufla.br/jspui/handle/1/41845 | |
| dc.identifier.uri | https://repositorioslatinoamericanos.uchile.cl/handle/2250/9045741 | |
| dc.description | A similar effect to the well-known reverse Perlin effect was observed on the 1JC–F coupling constants of α- and β-d-glucopyranosyl fluoride tetracetate, both in nonpolar and polar solution. This can be called “reverse fluorine Perlin-like effect”, and it is shown to be ruled by dipolar interactions rather than by hyperconjugation. The reverse fluorine Perlin-like effect does not have a general relationship with the anomeric effect, and it can be useful to determine the structure and stereochemistry of organofluorine compounds. | |
| dc.language | en_US | |
| dc.publisher | American Chemical Society (ACS) | |
| dc.rights | restrictAccess | |
| dc.source | Journal of Organic Chemistry (JOC) | |
| dc.subject | Electrostatics | |
| dc.subject | Fluorine | |
| dc.subject | Molecular properties | |
| dc.subject | Molecular structure | |
| dc.subject | Gases | |
| dc.title | The reverse fluorine Perlin-like effect and related stereoelectronic interactions | |
| dc.type | Artigo |