cis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine](dichloride) palladium(II)-based electrolyte membrane reactors for partial oxidation methane to methanol

dc.creatorGARCIA, LUIS M.S.
dc.creatorZAMBIAZI, PRISCILLA J.
dc.creatorCHAIR, KHAOULA
dc.creatorDOAN, TUAN D.
dc.creatorRAMOS, ANDREZZA S.
dc.creatorNANDENHA, JULIO
dc.creatorSOUZA, RODRIGO F.B. de
dc.creatorOTUBO, LARISSA
dc.creatorDUONG, ADAM
dc.creatorNETO, ALMIR O.
dc.date2022
dc.date2022-11-30T13:22:56Z
dc.date2022-11-30T13:22:56Z
dc.date.accessioned2023-09-28T14:23:28Z
dc.date.available2023-09-28T14:23:28Z
dc.identifier2470-1343
dc.identifierhttp://repositorio.ipen.br/handle/123456789/33361
dc.identifier28
dc.identifier7
dc.identifier10.1021/acsomega.2c01463
dc.identifier0000-0001-8745-3421
dc.identifier61.5
dc.identifier71.5
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9003580
dc.descriptionMethane is an abundant resource and the main constituent of natural gas. It can be converted into higher value-added products and as a subproduct of electricity co-generation. The application of polymer electrolyte reactors for the partial oxidation of methane to methanol to co-generate power and chemical products is a topic of great interest for gas and petroleum industries, especially with the use of materials with a lower amount of metals, such as palladium complex. In this study, we investigate the ideal relationship between cis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine(dichloride)palladium(II)] (Pd-complex) nanostructure and carbon to obtain a stable, conductive, and functional reagent diffusion electrode. The physical and structural properties of the material were analyzed by Fourier transform infrared (FT-IR) and Raman spectroscopies, transmission electron microscopy (TEM), and X-ray powder diffraction (XRD) techniques. The electrocatalytic activity studies revealed that the most active proportion was 20% of Pd-complex supported on carbon (m/m), which was measured with lower values of open-circuit and power density but with higher efficiency in methanol production with reaction rates of r = 4.2 mol L???1??h???1 at 0.05 V.
dc.descriptionConselho Nacional de Desenvolvimento Cient??fico e Tecnol??gico (CNPq)
dc.descriptionFunda????o de Amparo ?? Pesquisa do Estado de S??o Paulo (FAPESP)
dc.descriptionCNPq: 302709/2020-7
dc.descriptionFAPESP: 14/09087-4; 14/50279-4; 17/11937-4
dc.format24249-24255
dc.relationACS Omega
dc.rightsopenAccess
dc.subjectelectrolytes
dc.subjectfuel cells
dc.subjectmembranes
dc.subjectmethane
dc.subjectoxidation
dc.subjectelectrocatalysts
dc.titlecis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine](dichloride) palladium(II)-based electrolyte membrane reactors for partial oxidation methane to methanol
dc.typeArtigo de peri??dico
dc.coverageI


Este ítem pertenece a la siguiente institución