Oxidation of hydrocarbons with peroxides catalyzed by chromium(III) and iron(III) incorporated in SAPO-37 framework

dc.creatorSPINACE, ESTEVAM V.
dc.creatorSCHUCHARDT, ULF
dc.creatorCARDOSO, DILSON
dc.date1999
dc.date2016-11-10T15:19:15Z
dc.date2016-11-10T15:19:15Z
dc.date.accessioned2023-09-28T13:31:19Z
dc.date.available2023-09-28T13:31:19Z
dc.identifier0926-860X
dc.identifierhttp://repositorio.ipen.br/handle/123456789/26782
dc.identifier185
dc.identifier10.1016/S0926-860X(99)00192-1
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/8997077
dc.descriptionSAPO-37 containing structural chromium(III) and iron(III) ions were tested as catalysts in liquid phase oxidation of benzene and cyclohexane, using hydrogen peroxide and tert-butylhydroperoxide as oxidants. Only chromium(III) is active as oxidation catalyst. In spite of the SAPO-37 framework stability under the reaction conditions, leaching of small quantities of chromium occurs and the observed catalytic reaction is mainly due to the chromium ions in solution. ??1999 Elsevier Science B.V. All rights reserved.
dc.formatL193-L197
dc.relationApplied Catalysis A: General
dc.rightsopenAccess
dc.subjectoxidation
dc.subjecthydrocarbons
dc.subjectchromium
dc.subjectiron
dc.subjectsilicon phosphates
dc.subjectaluminium phosphates
dc.subjectliquids
dc.subjectbenzene
dc.subjectcyclohexane
dc.subjectredox reactions
dc.subjectmolecular ions
dc.titleOxidation of hydrocarbons with peroxides catalyzed by chromium(III) and iron(III) incorporated in SAPO-37 framework
dc.typeArtigo de peri??dico
dc.coverageI


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