dc.creatorBarbosa, Luiz Cláudio de Almeida
dc.creatorFerreira, Maria Lúcia
dc.creatorDemuner, Antonio Jacinto
dc.creatorSilva, Antonio Alberto da
dc.creatorPereira, Rita de Cássia
dc.date2019-05-03T13:05:36Z
dc.date2019-05-03T13:05:36Z
dc.date2001-11
dc.date.accessioned2023-09-27T22:04:06Z
dc.date.available2023-09-27T22:04:06Z
dc.identifier1678-7064
dc.identifierhttp://dx.doi.org/10.1590/S0100-40422001000600008
dc.identifierhttp://www.locus.ufv.br/handle/123456789/24975
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/8970211
dc.description3,5-Dimethoxybenzylic alcohol was converted into the 2-acetoxy-5-methoxy-3-(pent-1-yl)-1,4-benzoquinone (12), in seven steps, with an overall yield of 14.6%. The natural quinone sorgoleone (1) was isolated from Sorghum bicolor and converted into the corresponding quinone (13) having a saturated side chain. The selective effects of these compounds (1, 12 and 13), at the dose of 5.6 mg of a.i./ g of substrate, on the growth of Cucumis sativus, Lactuca sativa, Desmodium tortuosum, Hyptis suaveolens and Euphorbia heterophylla were evaluated. All three compounds caused some inhibition on the root growth of the test plants (0.0-69.19%) with the aerial parts less affected. The results showed that the triene unit of the sorgoleone side chain is not essential for the phytotoxicity and also the synthetic quinone was as active as the natural product.
dc.formatpdf
dc.formatapplication/pdf
dc.languageeng
dc.publisherQuímica Nova
dc.relationv. 24, n. 6, p. 751- 755, nov.- dec. 2001
dc.rightsOpen Access
dc.subjectQuinones
dc.subjectHerbicides
dc.subjectWeed
dc.titlePreparation and phytotoxicity of sorgoleone analogues
dc.typeArtigo


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