Ab initio study of thermoelectric properties of doped SnO2 superlattices

dc.creatorBorges, P. D.
dc.creatorSilva, D. E. S.
dc.creatorCastro, N. S.
dc.creatorFerreira, C. R.
dc.creatorPinto, F. G.
dc.creatorTronto, J.
dc.creatorScolfaro, L.
dc.date2018-09-06T13:00:11Z
dc.date2018-09-06T13:00:11Z
dc.date2015-11
dc.date.accessioned2023-09-27T21:42:20Z
dc.date.available2023-09-27T21:42:20Z
dc.identifier00224596
dc.identifierhttps://doi.org/10.1016/j.jssc.2015.08.024
dc.identifierhttp://www.locus.ufv.br/handle/123456789/21679
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/8964908
dc.descriptionTransparent conductive oxides, such as tin dioxide (SnO2), have recently shown to be promising materials for thermoelectric applications. In this work we studied the thermoelectric properties of Fe-, Sb- and Zn-uniformly doping and co-doping SnO2, as well as of Sb and Zn planar (or delta)-doped layers in SnO2 forming oxide superlattices (SLs). Based on the semiclassical Boltzmann transport equations (BTE) in conjunction with ab initio electronic structure calculations, the Seebeck coefficient (S) and figure of merit (ZT) are obtained for these systems, and are compared with available experimental data. The delta doping approach introduces a remarkable modification in the electronic structure of tin dioxide, when compared with the uniform doping, and colossal values for ZT are predicted for the delta-doped oxide SLs. This result is a consequence of the two-dimensional electronic confinement and the strong anisotropy introduced by the doped planes. In comparison with the uniformly doped systems, our predictions reveal a promising use of delta-doped SnO2 SLs for enhanced S and ZT, which emerge as potential candidates for thermoelectric applications.
dc.formatpdf
dc.formatapplication/pdf
dc.languagepor
dc.publisherJournal of Solid State Chemistry
dc.relationv. 231, p. 123- 131, november 2015
dc.rightsElsevier Inc.
dc.subjectThermoelectric materials
dc.subjectSnO2-based superlattices
dc.subjectAb initio calculations
dc.subjectBoltzmann transport
dc.titleAb initio study of thermoelectric properties of doped SnO2 superlattices
dc.typeArtigo


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