dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorTelis, V. R. Nicoletti
dc.creatorSobral, P. J. Do Amaral
dc.creatorTelis-Romero, J.
dc.date2014-05-27T11:21:52Z
dc.date2016-10-25T18:22:13Z
dc.date2014-05-27T11:21:52Z
dc.date2016-10-25T18:22:13Z
dc.date2006-06-01
dc.date.accessioned2017-04-06T01:18:51Z
dc.date.available2017-04-06T01:18:51Z
dc.identifierFood Science and Technology International, v. 12, n. 3, p. 181-187, 2006.
dc.identifier1082-0132
dc.identifier1532-1738
dc.identifierhttp://hdl.handle.net/11449/68898
dc.identifierhttp://acervodigital.unesp.br/handle/11449/68898
dc.identifier10.1177/1082013206065953
dc.identifierWOS:000237887300001
dc.identifier2-s2.0-33744768641
dc.identifier0000-0002-2553-4629
dc.identifierhttp://dx.doi.org/10.1177/1082013206065953
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/890207
dc.descriptionDifferential scanning calorimetry (DSC) was used to determine phase transitions of freeze-dried plums. Samples at low and intermediate moisture contents, were conditioned by adsorption at various water activities (0.11≤a w≤0.90) at 25°C, whereas in the high moisture content region (a w>0.90) samples were obtained by direct water addition, with the resulting sorption isotherm being well described by the Guggenheim-Anderson-deBoer (GAB) model. Freeze-dried samples of separated plum skin and pulp were also analysed. At a w≤0.75, two glass transitions were visible, with the glass transition temperature (T g) decreasing with increasing a w due to the water plasticising effect. The first T g was attributed to the matrix formed by sugars and water. The second one, less visible and less plasticised by water, was probably due to macromolecules of the fruit pulp. The Gordon-Taylor model represented satisfactorily the matrix glass transition curve for a w≤0.90. In the higher moisture content range T g remained practically constant around T g′ (-57.5°C). Analysis of the glass transition curve and the sorption isotherm indicated that stability at a temperature of 25°C, would be attained by freeze dried plum at a water activity of 0.04, corresponding to a moisture content of 12.9% (dry basis). © 2006 SAGE Publications.
dc.languageeng
dc.relationFood Science and Technology International
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectDifferential scanning calorimetry
dc.subjectGlass transition
dc.subjectIsotherms
dc.subjectMoisture
dc.subjectSorption
dc.subjectPlasticising effect
dc.subjectPlum
dc.subjectSorption isotherm
dc.subjectFruits
dc.subjectPrunus domestica
dc.titleSorption isotherm, glass transitions and state diagram for freeze-dried plum skin and pulp
dc.typeOtro


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