A description of ligand field effects in the Di-μ-Azido-Bis [{Azido(N,N-diethylethylenediamine)}Copper(II)] compound by the simple overlap model

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorMalta, O. L.
dc.creatorMauro, A. E.
dc.creatorMattioli, M. P D
dc.creatorSargentelli, V.
dc.creatorBrito, H. F.
dc.date2014-05-27T11:19:40Z
dc.date2016-10-25T18:15:26Z
dc.date2014-05-27T11:19:40Z
dc.date2016-10-25T18:15:26Z
dc.date1998-12-01
dc.date.accessioned2017-04-06T00:53:13Z
dc.date.available2017-04-06T00:53:13Z
dc.identifierJournal of the Brazilian Chemical Society, v. 9, n. 3, p. 243-247, 1998.
dc.identifier0103-5053
dc.identifierhttp://hdl.handle.net/11449/65627
dc.identifierhttp://acervodigital.unesp.br/handle/11449/65627
dc.identifier10.1590/S0103-50531998000300007
dc.identifierS0103-50531998000300007
dc.identifierWOS:000075978400007
dc.identifier2-s2.0-0032329824.pdf
dc.identifier2-s2.0-0032329824
dc.identifierhttp://dx.doi.org/10.1590/S0103-50531998000300007
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/887328
dc.descriptionWe present a theoretical description of ligand field effects in the di-μ-azido- bis[{azido(N,N-diethylethylenediamine)} copper(II)] compound by the Simple Overlap Model. The ligand field Hamiltonian is expressed in terms of irreducible tensor operators for an assumed D3h site symmetry occupied by the copper ion. The ligand field parameters, calculated from the available structural data, indicate that the copper ion is under the influence of a very strong ligand field. The energy of the d-d absorption band is well reproduced phenomenologically by the model.
dc.languageeng
dc.relationJournal of the Brazilian Chemical Society
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAmine ligands
dc.subjectComplexes
dc.subjectCopper(II)
dc.subjectLigand field
dc.titleA description of ligand field effects in the Di-μ-Azido-Bis [{Azido(N,N-diethylethylenediamine)}Copper(II)] compound by the simple overlap model
dc.typeOtro


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