Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorArantes, Francisco C. C.
dc.creatorMoro, Antonio C.
dc.creatorKlein, Iolanda S.
dc.creatorda Silva, Cristiana
dc.creatorNetto, Adelino Vieira de Godoy
dc.creatorMauro, Antonio Eduardo
dc.creatorNogueira, Vânia Martins
dc.date2014-05-20T15:31:11Z
dc.date2016-10-25T18:06:56Z
dc.date2014-05-20T15:31:11Z
dc.date2016-10-25T18:06:56Z
dc.date2011-11-01
dc.date.accessioned2017-04-06T00:20:56Z
dc.date.available2017-04-06T00:20:56Z
dc.identifierJournal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 379-383, 2011.
dc.identifier1388-6150
dc.identifierhttp://hdl.handle.net/11449/40387
dc.identifierhttp://acervodigital.unesp.br/handle/11449/40387
dc.identifier10.1007/s10973-010-1228-4
dc.identifierWOS:000296065100012
dc.identifierhttp://dx.doi.org/10.1007/s10973-010-1228-4
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/883169
dc.descriptionThe synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)(2)(mtu)(PPh3)] (X = Cl- (1), SCN- (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)(2)(phtu)(PPh3)] (X = Cl- (3), SCN- (4); phtu = N-phenylthiourea) are described. The thermal decomposition of the compounds occurs in two, three, or four stages and the final decomposition products were identified as Pd-0 by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3 > 2 > 1.
dc.languageeng
dc.publisherSpringer
dc.relationJournal of Thermal Analysis and Calorimetry
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectPalladium (II) compounds
dc.subjectThioureas
dc.subjectPseudohalides
dc.subjectThermal analysis
dc.titleThermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)
dc.typeOtro


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