dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorMessaddeq, S. H.
dc.creatorMastelaro, V. R.
dc.creatorLi, M. S.
dc.creatorTabackniks, M.
dc.creatorLezal, D.
dc.creatorRamos, A.
dc.creatorMessaddeq, Younes
dc.date2014-05-20T15:27:04Z
dc.date2016-10-25T18:01:47Z
dc.date2014-05-20T15:27:04Z
dc.date2016-10-25T18:01:47Z
dc.date2003-01-31
dc.date.accessioned2017-04-06T00:00:03Z
dc.date.available2017-04-06T00:00:03Z
dc.identifierApplied Surface Science. Amsterdam: Elsevier B.V., v. 205, n. 1-4, p. 143-150, 2003.
dc.identifier0169-4332
dc.identifierhttp://hdl.handle.net/11449/37117
dc.identifierhttp://acervodigital.unesp.br/handle/11449/37117
dc.identifier10.1016/S0169-4332(02)01013-9
dc.identifierWOS:000180675100018
dc.identifierhttp://dx.doi.org/10.1016/S0169-4332(02)01013-9
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/880483
dc.descriptionIrreversible photoexpansion and photobleaching effect has been observed in amorphous Ga10Ge25S65 glass when its surface was exposed to light with energy greater than the band gap, 3.52 eV. The magnitude of the expansion of GaGeS glasses depends on the exposure conditions. Extended X-ray absorption fine structure (EXAFS) spectroscopy and Rutherford backscattering spectrometry (RBS) have been used to identify the chemical nature of the glass samples before and after illumination. The quantitative analysis of the EXAFS data leads to a two-shell model of 0.5 oxygen atoms at 2.01 Angstrom and 3.6 sulfur atoms at a 2.20 Angstrom. RBS technique demonstrated that chemical composition of the glass surface after irradiation is oxygen rich. The existence of Ge-O bonds in the glass after illumination was also confirmed by infrared measurements. (C) 2002 Elsevier B.V. B.V. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationApplied Surface Science
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectchalcogenide glasses
dc.subjectphotoexpansion
dc.subjectoxygen
dc.subjectEXAFS
dc.subjectRBS
dc.titleThe influence of oxygen in the photoexpansion of GaGeS glasses
dc.typeOtro


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