dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorPereira, Francisco Claudece
dc.creatorZanoni, Maria Valnice Boldrin
dc.date2014-05-20T15:24:45Z
dc.date2016-10-25T17:59:03Z
dc.date2014-05-20T15:24:45Z
dc.date2016-10-25T17:59:03Z
dc.date2007-05-01
dc.date.accessioned2017-04-05T23:48:55Z
dc.date.available2017-04-05T23:48:55Z
dc.identifierElectroanalysis. Weinheim: Wiley-v C H Verlag Gmbh, v. 19, n. 9, p. 993-998, 2007.
dc.identifier1040-0397
dc.identifierhttp://hdl.handle.net/11449/35298
dc.identifierhttp://acervodigital.unesp.br/handle/11449/35298
dc.identifier10.1002/elan.200603815
dc.identifierWOS:000246534700013
dc.identifier0000-0002-2296-1393
dc.identifierhttp://dx.doi.org/10.1002/elan.200603815
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/879056
dc.descriptionSodium nitroprusside (NP), a commercial vasodilator, can be pre-concentrated on vitreous carbon electrode modified by films of 97.5%: 2.5% Poly-L-lysine (PLL): glutaraldehyde (GA). This coating gives acceptable anion exchange properties whilst giving the required improvement of adhesion to the glassy carbon electrode surface. Linear response range and detection limit on nitroprusside in B-R buffer pH 4.0, were 1 x 10(-6) to 2 x 10-(5) mol L-1 and 1 x 10(-7) mol L-1, respectively. The repeatability of the proposed sensor, evaluated in term of relative standard deviation, was measured as 4.1% for 10 experiments. The voltammetric sensor was directly applied to determination of nitroprusside in human plasma and urine samples and the average recovery for these samples was around 95-97% without any pre treatment.
dc.languageeng
dc.publisherWiley-Blackwell
dc.relationElectroanalysis
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectvoltammetric sensor
dc.subjectpoly-L-lysine
dc.subjectnitroprusside
dc.subjectbiological fluids
dc.titleVoltammetric sensor for sodium nitroprusside determination in biological fluids using films of poly-L-lysine
dc.typeOtro


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