An investigation of the thermal behavior of heterobimetallic species containing copper(II) and tetracyanopalladate(II)

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorLegendre, A. O.
dc.creatorCorrea, J. R. A.
dc.creatorBannach, G.
dc.creatorMauro, Antonio Eduardo
dc.creatorIonashiro, Massao
dc.date2014-05-20T15:22:52Z
dc.date2016-10-25T17:56:40Z
dc.date2014-05-20T15:22:52Z
dc.date2016-10-25T17:56:40Z
dc.date2007-03-01
dc.date.accessioned2017-04-05T23:39:03Z
dc.date.available2017-04-05T23:39:03Z
dc.identifierJournal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 87, n. 3, p. 779-782, 2007.
dc.identifier1388-6150
dc.identifierhttp://hdl.handle.net/11449/33780
dc.identifierhttp://acervodigital.unesp.br/handle/11449/33780
dc.identifier10.1007/s10973-006-7858-x
dc.identifierWOS:000244823700033
dc.identifierhttp://dx.doi.org/10.1007/s10973-006-7858-x
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/877824
dc.descriptionSynthesis, characterization and thermal behavior of four compounds that have the general formula [Cu{Pd(CN)(4)}(L)(x)](n), in which en = 1,2-diaminoethane and pn = 1,3-diaminopropane (L = en, x = 1 (I); L = pn, x = 1 (II); L = en, x = 2 (III); L = pn, x = 2 (IV)) were described in this work. The complexes were studied by elemental analysis, infrared spectroscopy (IR), differential thermal analysis (DTA) and thermogravimetry (TG) and the residues of the thermal decomposition were characterized by X-ray powder diffraction and found as a mixture of CuO and PdO. The stoichiometry of the compounds was established via thermogravimetric and elemental analyses and their structures were proposed as coordination polymers based on their infrared spectra. The following thermal stability sequence was found: IV < I=II < III.
dc.languageeng
dc.publisherSpringer
dc.relationJournal of Thermal Analysis and Calorimetry
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectamines
dc.subjectcopper(II) complexes
dc.subjecttetracyanopalladate(II)
dc.subjectthermal behavior
dc.titleAn investigation of the thermal behavior of heterobimetallic species containing copper(II) and tetracyanopalladate(II)
dc.typeOtro


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