Self-assembly of organometallic Pd(II) complexes via CH3 center dot center dot center dot pi interactions: the first example of a cyclopalladated compound with herringbone stacking pattern

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorde Almeida, E. T.
dc.creatorMauro, A. E.
dc.creatorSantana, A. M.
dc.creatorAnanias, S. R.
dc.creatorNetto, A. V. G.
dc.creatorFerreira, J. G.
dc.creatorSantos, R. H. A.
dc.date2014-05-20T15:20:33Z
dc.date2016-10-25T17:53:42Z
dc.date2014-05-20T15:20:33Z
dc.date2016-10-25T17:53:42Z
dc.date2007-12-01
dc.date.accessioned2017-04-05T23:26:30Z
dc.date.available2017-04-05T23:26:30Z
dc.identifierInorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 10, n. 12, p. 1394-1398, 2007.
dc.identifier1387-7003
dc.identifierhttp://hdl.handle.net/11449/31832
dc.identifierhttp://acervodigital.unesp.br/handle/11449/31832
dc.identifier10.1016/j.inoche.2007.08.020
dc.identifierWOS:000251977500002
dc.identifierhttp://dx.doi.org/10.1016/j.inoche.2007.08.020
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/876296
dc.descriptionTwo binuclear cyclometallated compounds [Pd(C-2,N-dmba)(mu-N-3)](2) (1) and [Pd-2(C-2,N-dmba)(2)(mu-N-3)(mu-Cl)] (2) (dmba = N,N-dimethylbenzylarnine) have been synthesized and characterized by elemental 3 analysis, IR and NMR spectroscopies and single crystal X-ray diffraction crystallography. The ability of CH3 groups to form C(sp(3))-H...pi hydrogen bonds with phenyl rings is responsible for the molecular self-assembly within the crystals of 1 and 2. Compound 1 crystallizes as one-dimensional supramolecular chains whereas the crystal packing of 2 consists of a herringbone of sandwiches composed by two inversely related [Pd-2(C-2,N-dmba)(2)(mu-N-3)(mu-Cl)] molecules. (c) 2007 Elsevier B.V. All rights reserved.
dc.languageeng
dc.publisherElsevier B.V.
dc.relationInorganic Chemistry Communications
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectsupramolecular chemistry
dc.subjectC(sp(3))-H...pi interactions
dc.subjectcyclopalladated compounds
dc.subjectself-assembly
dc.titleSelf-assembly of organometallic Pd(II) complexes via CH3 center dot center dot center dot pi interactions: the first example of a cyclopalladated compound with herringbone stacking pattern
dc.typeOtro


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